209384
3-甲氧基氯苄
97%
别名:
3-(氯甲基)苯甲醚
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关于此项目
线性分子式:
CH3OC6H4CH2Cl
化学文摘社编号:
分子量:
156.61
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
636684
产品名称
3-甲氧基氯苄, 97%
InChI
1S/C8H9ClO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
SMILES string
COc1cccc(CCl)c1
InChI key
VGISFWWEOGVMED-UHFFFAOYSA-N
assay
97%
form
liquid
contains
potassium carbonate as stabilizer
refractive index
n20/D 1.544 (lit.)
bp
124 °C/13 mmHg (lit.)
density
1.078 g/mL at 25 °C (lit.)
1.078 g/mL
functional group
chloro
storage temp.
2-8°C
Quality Level
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Application
3-Methoxybenzyl chloride was used to alkylate 8-benzyloxy-2(1H)-quinolinone in the presence of DMF and NaH. It was also used in the synthesis of diarylmethanes via in situ organozinc-mediated, palladium-catalyzed cross-coupling between benzyl and aryl halide.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
N-vs O-Alkylation in 2 (1H)-quinolinone derivatives.
Guo Z-X, et al.
Tetrahedron Letters, 40(38), 6999-7002 (1999)
Christophe Duplais et al.
Chemical communications (Cambridge, England), 46(4), 562-564 (2010-01-12)
A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are
Prachi Singh et al.
SLAS discovery : advancing life sciences R & D, 22(4), 440-446 (2017-03-23)
Analysis of interactions between molecules is of fundamental importance in life science research. In this study, we applied weak affinity chromatography, based on high-performance liquid chromatography and mass spectrometry, as a powerful tool for direct analysis of the components of
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