213012
苯亚硒酸酐
70%
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
C6H5SeOOSeOC6H5
化学文摘社编号:
分子量:
360.13
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
2332406
MDL number:
产品名称
苯亚硒酸酐, 70%
SMILES string
O=[Se](O[Se](=O)c1ccccc1)c2ccccc2
InChI
1S/C12H10O3Se2/c13-16(11-7-3-1-4-8-11)15-17(14)12-9-5-2-6-10-12/h1-10H
InChI key
FHPZOWOEILXXBD-UHFFFAOYSA-N
assay
70%
form
powder
impurities
<30% benzeneseleninic acid
mp
165-170 °C (lit.)
正在寻找类似产品? 访问 产品对比指南
Application
用苯甲烯酐酸酐可通过氧化肼得到偶氮化合物。
General description
苯硒酸酐氧化苯酚可产生 邻位-醌。苯硒酸酐可作为温和的氧化剂，用于将苄基烃转化为醛或酮。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Preparation of aldehydes and ketones by oxidation of benzylic hydrocarbons with benzeneseleninic anhydride.
Barton DHR, et al.
Tetrahedron Letters, 20(35), 3331-3334 (1979)
Dehydrogenation of hydrazines and of 4-azacholestan-3-one with benzeneseleninic acid and benzeneseleninic anhydride.
Back TG.
Journal of the Chemical Society. Chemical Communications, 6, 278-279 (1978)
Comparative oxidation of phenols with benzeneseleninic anhydride and with benzeneseleninic acid.
Barton DHR, et al.
Tetrahedron, 44(20), 6397-6406 (1988)
T Iida et al.
Journal of lipid research, 29(8), 1097-1101 (1988-08-01)
A facile one-step conversion of stereoisomeric methyl 3-hydroxycholanoates to 1,4-dien-3-one, by treatment in boiling toluene with iodoxybenzene catalyzed by benzeneselenic anhydride, is described. The direct oxidation-dehydrogenation at C-3 is applicable to other cholanoates (hyodeoxycholic, chenodeoxycholic, ursodeoxycholic, deoxycholic, and cholic) when
Naotoshi Toki et al.
Chemical & pharmaceutical bulletin, 52(8), 1009-1012 (2004-08-12)
Benzeneseleninic anhydride in the presence of tert-butyl hydroperoxide in chlorobenzene at about 70 degrees C is an effective oxidizing agent for the selective oxidation of alcohols at the benzylic position.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持