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经验公式(希尔记法):
C10H10N2 · H2Cr2O7
化学文摘社编号:
分子量:
376.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
243-478-8
MDL number:
产品名称
重铬酸吡啶鎓, 98%
InChI key
RCBVKBFIWMOMHF-UHFFFAOYSA-L
InChI
1S/2C5H5N.2Cr.2H2O.5O/c2*1-2-4-6-5-3-1;;;;;;;;;/h2*1-5H;;;2*1H2;;;;;/q;;2*+1;;;;;;;/p-2
SMILES string
c1ccncc1.c2ccncc2.O[Cr](=O)(=O)O[Cr](O)(=O)=O
assay
98%
form
solid
reaction suitability
reagent type: oxidant
mp
152-153 °C (lit.)
Quality Level
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Application
在叔丁基过氧化氢(货号 213128)存在下,将伯醇转化为醛和酮,将缩醛转化为酯,将双脱氢酮转化为烯酮的氧化剂。
General description
重铬酸吡啶是一种吡啶盐和强氧化剂,可将伯醇和仲醇分别转化为醛和酮。
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
J. Mol. Catal. A: Chem., 250, 70-70 (2006)
Yihui Zhou et al.
Environmental pollution (Barking, Essex : 1987), 219, 932-938 (2016-10-07)
In this study, polybrominated diphenyl ethers (PBDEs) and methoxylated polybrominated diphenyl ethers (MeO-PBDEs) were analyzed in eleven freshwater fish species from Dianshan Lake, Shanghai, China. The highest concentrations of PBDEs and MeO-PBDEs were found in snakehead, with mean values of
Yong-Hua Li et al.
Epilepsy research, 128, 149-157 (2016-11-14)
Localization of the epileptogenic zone (EZ) is essential for the successful surgical treatment of medically intractable epilepsy. In the present study, stereo-EEG (SEEG) recordings were obtained from seven patients underwent presurgical evaluation for treatment of intractable epilepsy. Partial directed coherence
Sameer Shivji et al.
Histopathology, 77(3), 351-368 (2020-05-03)
Poorly differentiated clusters (PDC), defined as small groups of ≥5 tumour cells without glandular differentiation, have gained recent attention as a promising prognostic factor in colorectal cancer (CRC). Numerous studies have shown PDC to be significantly associated with other adverse
Hong-Viet Ngo et al.
eLife, 9 (2020-07-14)
Sleep is pivotal for memory consolidation. According to two-stage accounts, memory traces are gradually translocated from hippocampus to neocortex during non-rapid-eye-movement (NREM) sleep. Mechanistically, this information transfer is thought to rely on interactions between thalamocortical spindles and hippocampal ripples. To
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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