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经验公式(希尔记法):
C10H10N2 · H2Cr2O7
化学文摘社编号:
分子量:
376.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
243-478-8
MDL number:
产品名称
重铬酸吡啶鎓, 98%
InChI key
RCBVKBFIWMOMHF-UHFFFAOYSA-L
InChI
1S/2C5H5N.2Cr.2H2O.5O/c2*1-2-4-6-5-3-1;;;;;;;;;/h2*1-5H;;;2*1H2;;;;;/q;;2*+1;;;;;;;/p-2
SMILES string
c1ccncc1.c2ccncc2.O[Cr](=O)(=O)O[Cr](O)(=O)=O
assay
98%
form
solid
reaction suitability
reagent type: oxidant
mp
152-153 °C (lit.)
Quality Level
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Application
在叔丁基过氧化氢(货号 213128)存在下,将伯醇转化为醛和酮,将缩醛转化为酯,将双脱氢酮转化为烯酮的氧化剂。
General description
重铬酸吡啶是一种吡啶盐和强氧化剂,可将伯醇和仲醇分别转化为醛和酮。
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Yihui Zhou et al.
Environmental pollution (Barking, Essex : 1987), 219, 932-938 (2016-10-07)
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J. Mol. Catal. A: Chem., 250, 70-70 (2006)
K M Halkes et al.
Carbohydrate research, 309(2), 161-174 (1998-09-19)
To contribute to the possibilities to study the ability of oligosaccharide fragments of hyaluronic acid to induce angiogenesis, several hyaluronic-acid-related oligosaccharides and their 6-O-sulfated analogues were synthesised as their 4-methoxyphenyl glycosides having 2-acetamido-2-deoxy-D-glucopyranose at the reducing end. In all syntheses
Dympna Leonard et al.
Nutrition & dietetics: the journal of the Dietitians Association of Australia, 75(5), 457-467 (2018-12-12)
Anaemia during pregnancy is common worldwide. In Australia between 7.1% and 11% of mothers have been reported to have anaemia in pregnancy. Higher rates are reported for Aboriginal and Torres Strait Islander women (Townsville: 34.2%, remote Northern Territory: 50%). The
Kinetics and mechanism of oxidation of pimary alcohols by pyridinium dichromate
Harit H, et al.
Chemical Science, 4, 49-58 (2015)
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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