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Merck
CN

214698

重铬酸吡啶鎓

98%

别名:

丙酮酸脱氢酶复合体

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关于此项目

经验公式(希尔记法):
C10H10N2 · H2Cr2O7
化学文摘社编号:
分子量:
376.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
EC Number:
243-478-8
MDL number:
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产品名称

重铬酸吡啶鎓, 98%

InChI key

RCBVKBFIWMOMHF-UHFFFAOYSA-L

InChI

1S/2C5H5N.2Cr.2H2O.5O/c2*1-2-4-6-5-3-1;;;;;;;;;/h2*1-5H;;;2*1H2;;;;;/q;;2*+1;;;;;;;/p-2

SMILES string

c1ccncc1.c2ccncc2.O[Cr](=O)(=O)O[Cr](O)(=O)=O

assay

98%

form

solid

reaction suitability

reagent type: oxidant

mp

152-153 °C (lit.)

Quality Level

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Application

丁基过氧化氢(货号 213128)存在下,将伯醇转化为醛和酮,将缩醛转化为酯,将双脱氢酮转化为烯酮的氧化剂。

General description

重铬酸吡啶是一种吡啶盐和强氧化剂,可将伯醇和仲醇分别转化为醛和酮。

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Skin Sens. 1

存储类别

4.1A - Other explosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J. Mol. Catal. A: Chem., 250, 70-70 (2006)
K M Halkes et al.
Carbohydrate research, 309(2), 161-174 (1998-09-19)
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Dympna Leonard et al.
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Kinetics and mechanism of oxidation of pimary alcohols by pyridinium dichromate
Harit H, et al.
Chemical Science, 4, 49-58 (2015)

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