214914
N,N-二甲基亚甲基碘化铵
98%
别名:
N,N-二甲基亚甲基碘化胺, Eschenmoser 盐
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关于此项目
线性分子式:
CH2=N+(CH3)2I-
化学文摘社编号:
分子量:
185.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-680-2
Beilstein/REAXYS Number:
1731022
MDL number:
Assay:
98%
InChI key
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
InChI
1S/C3H8N.HI/c1-4(2)3;/h1H2,2-3H3;1H/q+1;/p-1
SMILES string
[I-].C[N+](C)=C
assay
98%
mp
219 °C (dec.) (lit.)
solubility
water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
functional group
amine
Quality Level
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General description
N,N -二甲基亚甲基碘是许多合成应用的有用试剂 ， 尤其是氨基甲酰化和酮转化为 α,β-不饱和烯酮。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
A new method using 2-chloro-4, 6-dimethoxy-1, 3, 5-triazine for facile elimination of dimethylamino group in Eschenmoser's methylenation for synthesis of a, ?-unsaturated esters.
Yamada K, et al.
Tetrahedron Letters, 54(13), 1753-1760 (2013)
Masayuki Inoue et al.
The Journal of organic chemistry, 72(8), 3065-3075 (2007-03-16)
(-)-Merrilactone A [(-)-1], isolated from Illicium merrillianum in 2000, possesses neurite outgrowth activity in cultures of fetal rat cortical neurons, and, therefore, is expected to show therapeutic potential for the treatment of neurodegeneration associated with Alzheimer's and Parkinson's diseases. Apart
Tetrahedron Asymmetry, 5, 921-921 (1994)
Synthetic Routes to Unsymmetrical Porphyrins.
Nardis S.
Synthesis and Modifications of Porphyrinoids, 203-239 (2014)
Journal of the Chemical Society. Perkin Transactions 1, 3295-3295 (1992)
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