214914
N,N-二甲基亚甲基碘化铵
98%
别名:
N,N-二甲基亚甲基碘化胺, Eschenmoser 盐
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线性分子式:
CH2=N+(CH3)2I-
化学文摘社编号:
分子量:
185.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-680-2
Beilstein/REAXYS Number:
1731022
MDL number:
Assay:
98%
InChI key
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
InChI
1S/C3H8N.HI/c1-4(2)3;/h1H2,2-3H3;1H/q+1;/p-1
SMILES string
[I-].C[N+](C)=C
assay
98%
mp
219 °C (dec.) (lit.)
solubility
water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
functional group
amine
Quality Level
General description
N,N -二甲基亚甲基碘是许多合成应用的有用试剂 ， 尤其是氨基甲酰化和酮转化为 α,β-不饱和烯酮。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Journal of the Chemical Society. Perkin Transactions 1, 3295-3295 (1992)
Chem. Abstr., 120, 190555b-190555b (1994)
Synthetic Routes to Unsymmetrical Porphyrins.
Nardis S.
Synthesis and Modifications of Porphyrinoids, 203-239 (2014)
Tetrahedron Asymmetry, 5, 921-921 (1994)
A new method using 2-chloro-4, 6-dimethoxy-1, 3, 5-triazine for facile elimination of dimethylamino group in Eschenmoser's methylenation for synthesis of a, ?-unsaturated esters.
Yamada K, et al.
Tetrahedron Letters, 54(13), 1753-1760 (2013)
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