Merck
CN
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文件

218308

Sigma-Aldrich

α-环氧蒎烷

97%

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经验公式（希尔记法）:
C10H16O
CAS号:
1686-14-2
分子量:
152.23
EC 号:
216-869-6
MDL编号:
MFCD00066955
PubChem化学物质编号:
24853058

检测方案

97%

形式

liquid

折射率

n20/D 1.469 (lit.)

bp

102-103 °C/50 mmHg (lit.)

密度

0.964 g/mL at 25 °C (lit.)

SMILES string

CC1(C)[C@H]2CC3OC3(C)[C@@H]1C2

InChI

1S/C10H16O/c1-9(2)6-4-7(9)10(3)8(5-6)11-10/h6-8H,4-5H2,1-3H3/t6-,7-,8?,10?/m1/s1

InChI key

NQFUSWIGRKFAHK-BGPATTHWSA-N

相关类别

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

150.8 °F - closed cup

闪点(°C)

66 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Denis Linares et al.
Bioresource technology, 99(11), 4590-4596 (2007-09-15)
The feasibility of trans-2-methyl-5-isopropylhexa-2,5-dienoic acid (novalic acid) accumulation using the alpha-pinene degradation pathway of Pseudomonas rhodesiae CIP 107491 was studied. This appeared possible by using concentrated living bacterial cells produced under oxygen limitation with alpha-pinene as sole carbon source. The
H Zorn et al.
Journal of biotechnology, 107(3), 255-263 (2004-01-23)
When submerged cultured Pseudomonas fluorescens NCIMB 11761 was fed-batch supplemented with alpha-pinene oxide, a rapid formation of 2,6-dimethyl-5-methylene-hept-(2Z)-enal (I) (isonovalal) was observed. Biotransformation and isomerisation of (I) to the (2E)-isomer (II) (novalal) were enhanced by Lewatit OC 1064, a macroporous
A Boontawan et al.
Applied microbiology and biotechnology, 69(6), 643-649 (2005-08-10)
In this work the biotransformation of alpha-pinene oxide to isonovalal using resting cells of Pseudomonas fluorescens NCIMB 11671 was evaluated in a membrane bioreactor for biotransformations (MBB). Since the membrane area required to obtain optimum productivities was calculated to be
P Fontanille et al.
Applied microbiology and biotechnology, 60(5), 534-540 (2003-01-22)
Optimization studies on the synthesis of isonovalal from alpha-pinene oxide by Pseudomonas rhodesiae CIP 107491 operated in a biphasic medium are presented. Three key parameters are identified. The first is the need for a permeabilization of cells by freezing them
Apichat Boontawan et al.
Biotechnology progress, 21(6), 1680-1687 (2005-12-03)
Terpenoids are important compounds for the fragrance industry, and recently, biocatalytic methods have been developed to produce them from cheap monoterpenes, such as alpha-pinene oxide. The biotransformation of alpha-pinene oxide using resting cells of Pseudomonas fluorescens NCIMB 11671 produces isonovalal
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