220159
2,3-二甲基-2-丁烯
≥99%
别名:
四甲基乙烯
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关于此项目
线性分子式:
(CH3)2C=C(CH3)2
化学文摘社编号:
分子量:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-263-8
Beilstein/REAXYS Number:
1361357
MDL number:
Assay:
≥99%
Form:
liquid
InChI key
WGLLSSPDPJPLOR-UHFFFAOYSA-N
InChI
1S/C6H12/c1-5(2)6(3)4/h1-4H3
SMILES string
C\C(C)=C(\C)C
vapor pressure
215 mmHg ( 37.7 °C)
assay
≥99%
form
liquid
autoignition temp.
754 °F
Quality Level
refractive index
n20/D 1.412 (lit.)
bp
73 °C (lit.)
mp
−75 °C (lit.)
density
0.708 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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General description
2,3-二甲基-2-丁烯在黑暗中臭氧分解产生羟基自由基 。用流动管接口式紫外光电子能谱仪研究了臭氧与 2，3-二甲基-2-丁烯 (DMB) 的反应 。在 0°C 和-15°C 下，DMB 与四氟硼酸硫代阳离子自由基形成加合物 。
Application
2,3-二甲基-2-丁烯作为底物参与了 2-羟基-1,4-萘醌的光诱导分子转化 。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The Journal of Organic Chemistry, 58, 4614-4614 (1993)
Bing-Jun Zhao et al.
The Journal of organic chemistry, 71(10), 3737-3742 (2006-05-06)
Thianthrene cation radical tetrafluoroborate (Th*+ BF4-) has been found to add to 2,3-dimethyl-2-butene (DMB) at 0 degrees C and -15 degrees C. The adduct, 2,3-dimethyl-2,3-(5,10-thianthreniumdiyl)butane ditetrafluoroborate (12), was isolated at -15 degrees C, and its 1H NMR spectrum was recorded
Maryline Pflieger et al.
Environmental science & technology, 47(12), 6239-6246 (2013-05-15)
In order to investigate the heterogeneous oxidation kinetics of the herbicide terbuthylazine (TERB), a stable and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and optimized using a PTR-MS. TERB was adsorbed on silica particles
R Tolando et al.
Xenobiotica; the fate of foreign compounds in biological systems, 26(4), 425-435 (1996-04-01)
1. During anaerobic reductive incubation of liver microsomes, from either the pyridine- or phenobarbital-treated rat, with 1,1-dichloro-1-fluoroethane (HCFC-141b) in the presence of a NADPH-regenerating system, a time- and dose-dependent formation of reactive metabolites was detected as indicated by a depletion
L R Pohl et al.
Biochemical and biophysical research communications, 117(2), 367-371 (1983-12-16)
Although indirect evidence has suggested that liver microsomal cytochrome P-450 can reductively dehalogenate several compounds to carbene metabolites, there has been no direct proof for the formation of these reactive species. We report in this paper that carbenes can be
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