228982
苄基三甲基氯化铵
97%
别名:
Amberlite IRC 178(Cl), 三甲基苄基氯化铵, 苄基三甲基氯化铵（6CI）
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关于此项目
线性分子式:
C6H5CH2N(Cl)(CH3)3
化学文摘社编号:
分子量:
185.69
UNSPSC Code:
12352107
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-300-3
Beilstein/REAXYS Number:
3917255
MDL number:
产品名称
苄基三甲基氯化铵, 97%
InChI key
KXHPPCXNWTUNSB-UHFFFAOYSA-M
InChI
1S/C10H16N.ClH/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H/q+1;/p-1
SMILES string
[Cl-].C[N+](C)(C)Cc1ccccc1
assay
97%
mp
239 °C (dec.) (lit.)
Quality Level
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Application
苄基三甲基氯化铵可用作以下反应的相催化剂：
- 在 1,3-二氯-5,5-二甲基乙内酰脲 (DCH) 存在的情况下由硫醇和二硫化物合成烷基和芳基磺酰胺。
- 以过氧化氢为氧化剂，将苯甲醇选择性氧化为苯甲醛。
- 乙醇和月桂酸的酯化反应。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Muta. 2
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Convenient one-pot Synthesis of sulfonamides from thiols and disulfides using 1, 3-dichloro-5, 5-dimethylhydantoin (DCH)
Veisi Hojat
Bull. Korean Chem. Soc., 33(2), 383-386 (2012)
Kinetics of the reaction of ethanol and lauric acid catalyzed by deep eutectic solvent based on benzyltrimethylammonium chloride
Li Kun, et al.
The Canadian Journal of Chemical Engineering, 97(5), 1144-1151 (2019)
Kathrin Müller et al.
Analytical and bioanalytical chemistry, 412(20), 4867-4879 (2020-03-05)
Matrix effects have been shown to be very pronounced and highly variable in the analysis of mobile chemicals, which may severely exacerbate accurate quantification. These matrix effects, however, are still scarcely studied in combination with hydrophilic interaction liquid chromatography (HILIC)
Purushothaman Gopinath et al.
The Journal of organic chemistry, 74(16), 6291-6294 (2009-07-22)
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
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