234524
硫代氯甲酸苯酯
99%
别名:
氯甲基硫代苯酯
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关于此项目
线性分子式:
ClC(S)OC6H5
化学文摘社编号:
分子量:
172.63
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-736-4
Beilstein/REAXYS Number:
774830
MDL number:
产品名称
硫代氯甲酸苯酯, 99%
InChI key
KOSYAAIZOGNATQ-UHFFFAOYSA-N
InChI
1S/C7H5ClOS/c8-7(10)9-6-4-2-1-3-5-6/h1-5H
SMILES string
ClC(=S)Oc1ccccc1
assay
99%
form
liquid
refractive index
n20/D 1.581 (lit.)
bp
81-83 °C/6 mmHg (lit.)
density
1.248 g/mL at 25 °C (lit.)
functional group
chloro
phenoxy
Quality Level
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Application
O -百菌清甲酸苯酯已用于：
- 立体定向合成光学活性，(-)-薄荷内酯
- 肽 α 的合成-具有多种 C -末端氨基酸的硫酯
- 司可洛 -肌醇衍生物的合成
- 无保护胸腺嘧啶核苷的硫代羰基化
- 受保护核苷的苯氧基硫代羰基酯的制备
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
177.8 °F - closed cup
flash_point_c
81 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Canadian Journal of Chemistry, 71, 186-186 (1993)
Total synthesis of (-)-mintlactone.
Carda M and Marco JA.
Tetrahedron Letters, 32(38), 5191-5192 (1991)
A synthetic approach to a peptide α-thioester from an unprotected peptide through cleavage and activation of a specific peptide bond by N-acetylguanidine.
Ryo Okamoto et al.
Angewandte Chemie (International ed. in English), 51(1), 191-196 (2011-11-19)
Synlett, 221-221 (1993)
Yedi Sun et al.
Bioorganic & medicinal chemistry, 16(15), 7177-7184 (2008-07-19)
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