235822
间氟苯腈
98%
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关于此项目
线性分子式:
FC6H4CN
化学文摘社编号:
分子量:
121.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-963-5
MDL number:
Assay:
98%
Form:
liquid
InChI key
JZTPKAROPNTQQV-UHFFFAOYSA-N
InChI
1S/C7H4FN/c8-7-3-1-2-6(4-7)5-9/h1-4H
SMILES string
Fc1cccc(c1)C#N
assay
98%
form
liquid
refractive index
n20/D 1.5043 (lit.)
bp
182-183 °C/753 mmHg (lit.)
mp
−16 °C (lit.)
density
1.133 g/mL at 25 °C (lit.)
functional group
fluoro, nitrile
Application
3-Fluorobenzonitrile has been used in the preparation of bis(3-cyanophenoxy)phenylenes.
General description
Microwave spectrum of 3-fluorobenzonitrile has been studied. Amination of 3-fluorobenzonitrile with morpholine in DMSO at 100°C has been investigated.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
154.4 °F - closed cup
flash_point_c
68 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Improved yields of meta-amination and symmetrical and unsymmetrical diamination of benzenes.
Brown GR, et al.
Tetrahedron Letters, 42(23), 3917-3919 (2001)
Synthesis of bis (ether nitrile) s and bis (ether acid) s from simplearomatic diols bymeta-fluoro displacement from3-fluorobenzonitrile.
Eastmond GC and Paprotny J.
Journal of Materials Chemistry, 7(8), 1321-1326 (1997)
Xiaotong Cheng et al.
The Journal of clinical investigation, 130(5), 2237-2251 (2020-01-31)
Hypoxia-inducible factor (HIF) is strikingly upregulated in many types of cancer, and there is great interest in applying inhibitors of HIF as anticancer therapeutics. The most advanced of these are small molecules that target the HIF-2 isoform through binding the
Microwave spectral study of 3-fluorobenzonitrile.
Dutta A, et al.
Journal of Molecular Spectroscopy, 118(1), 232-236 (1986)
Oriol Planas et al.
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner
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