237744
(S)-(+)-1,2-异亚丙基甘油
98%, optical purity ee: 99% (GLC)
别名:
(S)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醇, 1,2-Isopropylidene-sn-glycerol, D-α,β-异亚丙基甘油, D-(+)-丙酮缩甘油, D-1,2-O-isopropylidene-sn-glycerol
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关于此项目
经验公式（希尔记法）:
C6H12O3
化学文摘社编号:
分子量:
132.16
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
244-910-8
Beilstein/REAXYS Number:
80118
MDL number:
产品名称
(S)-(+)-1,2-异亚丙基甘油, 98%, optical purity ee: 99% (GLC)
InChI key
RNVYQYLELCKWAN-YFKPBYRVSA-N
InChI
1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3/t5-/m0/s1
SMILES string
CC1(C)OC[C@H](CO)O1
assay
98%
form
liquid
optical activity
[α]20/D +13.5°, neat
optical purity
ee: 99% (GLC)
refractive index
n20/D 1.434 (lit.)
bp
82-83 °C/14 mmHg (lit.)
density
1.07 g/mL at 25 °C (lit.)
functional group
ether
hydroxyl
ketal
storage temp.
2-8°C
Quality Level
Application
在利用GC对甘油和丙酮的缩酮化反应中丙酮缩甘油的产量和甘油转化率进行分析时，(S)-(+)-1,2-异丙叉甘油可用作校正标准品。它还可被用于合成1,2-二棕榈酰基-3-苄基-sn-甘油以及1-O-(Z)-十八碳烯基-sn-甘油，一种用于缩醛磷脂合成的中间体。
用于由 α,β-环氧砜通过 SO2 脱去反应合成手性烯丙基三醇。
General description
(S)-(+)-1,2-异丙叉甘油是合成甘油酯和磷酸甘油酯的一种关键构成单位。
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additive.
Nanda MR, et al.
Fuel: The Science and Technology of Fuel and Energy, 117, 470-477 (2014)
European Journal of Organic Chemistry, 1740-1740 (2006)
[58] Synthesis of labeled phospholipids in high yield.
Eibl H, et al.
Methods in Enzymology, 98, 623-632 (1983)
An improved method for the preparation of 1, 2-isopropylidene-sn-glycerol.
Eibl H.
Chemistry and Physics of Lipids, 28(1), 1-5 (1981)
Daria Tretiakova et al.
Current drug delivery, 17(4), 312-323 (2020-02-15)
Recently we developed a scalable scheme of synthesis of melphalan ester conjugate with 1,2-dioleoyl-sn-glycerol (MlphDG) and a protocol for the fabrication of its lyophilized liposomal formulation. Herein we compared this new convenient in use formulation of MlphDG with parent drug
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