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线性分子式:
CH3(CH2)11I
化学文摘社编号:
分子量:
296.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-293-1
Beilstein/REAXYS Number:
1738943
MDL number:
产品名称
1-碘十二烷, 98%
InChI key
GCDPERPXPREHJF-UHFFFAOYSA-N
InChI
1S/C12H25I/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
SMILES string
CCCCCCCCCCCCI
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.484 (lit.)
bp
159-160 °C/15 mmHg (lit.)
mp
−3 °C (lit.)
density
1.201 g/mL at 25 °C (lit.)
functional group
alkyl halide
iodo
Quality Level
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Application
1-碘十二烷已被用于合成:
- 十二烷基石墨
- 烷基官能化的单壁碳纳米管(SWNT)
General description
已经研究了在LiBr、LiCl和六甲基磷酰胺(HMPA)存在下SmI2介导的1-碘十二烷 和2-辛酮的偶联。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Robin E Anderson et al.
Journal of nanoscience and nanotechnology, 7(10), 3436-3440 (2008-03-12)
Single walled carbon nanotubes (SWNTs) may be made soluble in a range of organic solvents without sidewall functionalization via their reduction by Na/Hg amalgam in the presence of dibenzo-18-crown-6. The [Na(dibenzo-18-crown-6)]n[SWNT] complex has been characterized by UV-Visible, Raman, and AFM
Reactions of SmI2 with alkyl halides and ketones: Inner-sphere vs outer-sphere electron transfer in reactions of Sm (II) reductants.
Miller RS, et al.
Journal of the American Chemical Society, 122(32), 7718-7722 (2000)
Minhuan Li et al.
Science advances, 6(27), eaaw8938-eaaw8938 (2020-07-14)
Most systems have more than two stable crystalline states in the phase diagram, which is known as polymorphism. Crystallization in such a system is often under strong influence of competing orderings linked to those crystals. However, how such competition affects
Functionalization of potassium graphite.
Soma Chakraborty et al.
Angewandte Chemie (International ed. in English), 46(24), 4486-4488 (2007-05-05)
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
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