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线性分子式:
CH3(CH2)11I
化学文摘社编号:
分子量:
296.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-293-1
Beilstein/REAXYS Number:
1738943
MDL number:
产品名称
1-碘十二烷, 98%
InChI key
GCDPERPXPREHJF-UHFFFAOYSA-N
InChI
1S/C12H25I/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
SMILES string
CCCCCCCCCCCCI
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.484 (lit.)
bp
159-160 °C/15 mmHg (lit.)
mp
−3 °C (lit.)
density
1.201 g/mL at 25 °C (lit.)
functional group
alkyl halide
iodo
Quality Level
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Application
1-碘十二烷已被用于合成:
- 十二烷基石墨
- 烷基官能化的单壁碳纳米管(SWNT)
General description
已经研究了在LiBr、LiCl和六甲基磷酰胺(HMPA)存在下SmI2介导的1-碘十二烷 和2-辛酮的偶联。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Robin E Anderson et al.
Journal of nanoscience and nanotechnology, 7(10), 3436-3440 (2008-03-12)
Single walled carbon nanotubes (SWNTs) may be made soluble in a range of organic solvents without sidewall functionalization via their reduction by Na/Hg amalgam in the presence of dibenzo-18-crown-6. The [Na(dibenzo-18-crown-6)]n[SWNT] complex has been characterized by UV-Visible, Raman, and AFM
Reactions of SmI2 with alkyl halides and ketones: Inner-sphere vs outer-sphere electron transfer in reactions of Sm (II) reductants.
Miller RS, et al.
Journal of the American Chemical Society, 122(32), 7718-7722 (2000)
Functionalization of potassium graphite.
Soma Chakraborty et al.
Angewandte Chemie (International ed. in English), 46(24), 4486-4488 (2007-05-05)
Minhuan Li et al.
Science advances, 6(27), eaaw8938-eaaw8938 (2020-07-14)
Most systems have more than two stable crystalline states in the phase diagram, which is known as polymorphism. Crystallization in such a system is often under strong influence of competing orderings linked to those crystals. However, how such competition affects
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
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