238732
三氟乙酸铵
98%
别名:
三氟乙酸 铵盐
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关于此项目
线性分子式:
CF3CO2NH4
化学文摘社编号:
分子量:
131.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
222-072-4
MDL number:
Assay:
98%
Form:
crystals
InChI key
YCNIBOIOWCTRCL-UHFFFAOYSA-N
InChI
1S/C2HF3O2.H3N/c3-2(4,5)1(6)7;/h(H,6,7);1H3
SMILES string
N.OC(=O)C(F)(F)F
assay
98%
form
crystals
mp
123-125 °C (lit.)
functional group
carboxylic acid, fluoro
Quality Level
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General description
三氟乙酸铵被用作有机合成中的催化剂，以及手性外消旋物分离的流动相添加剂。
Application
用于合成六氟-2-氨基戊-4-酮配体，以及调节和校准新的液谱/质谱系统。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Journal of Fluorine Chemistry, 27, 371-371 (1985)
Nimisha Thakur et al.
Chirality, 31(9), 688-699 (2019-07-19)
The enantiomeric excess of chiral starting materials is one of the important factors determining the enantiopurity of products in asymmetric synthesis. Fifty-one commercially available chiral reagents used as building blocks, catalysts, and auxiliaries in various enantioselective syntheses were assayed for
Jie Wang et al.
Biomedical chromatography : BMC, 33(3), e4438-e4438 (2018-11-18)
Tanshinol borneol ester (DBZ) is a potential drug candidate composed of danshensu and borneol. It shows anti-ischemic and anti-atherosclerosis activity. However, little is known about its metabolism in vivo. This research aimed to elucidate the metabolic profile of DBZ through
Applications of ammonium trifluoroacetate as an additive for elution of chiral acids and bases from derivatized polysaccharide stationary phases
Neville H L et al.
Chirality, 17, S84-S92 (2005)
Garrett Hellinghausen et al.
Journal of pharmaceutical and biomedical analysis, 155, 70-81 (2018-04-07)
Core-shell particles (superficially porous particles, SPPs) have been proven to provide high-throughput and effective separations of a variety of chiral molecules. However, due to their limited commercialization, many separations have not been reported with these stationary phases. In this study
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