Merck
CN
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文件

安全信息

241997

Sigma-Aldrich

1-戊烯

98%

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别名:
α-n-Amylene, 1-Methyl-3-butene, 4-Methyl-1-butene, Propylethylene
线性分子式:
CH3CH2CH2CH=CH2
CAS号:
109-67-1
分子量:
70.13
Beilstein:
1731629
EC 号:
203-694-5
MDL编号:
MFCD00003567
PubChem化学物质编号:
24854526
NACRES:
NA.22

蒸汽密度

2.4 (vs air)

蒸汽压

10.27 psi ( 20 °C)

检测方案

98%

形式

liquid

自燃温度

522 °F

expl. lim.

8.7 %

折射率

n20/D 1.371 (lit.)

bp

29.9-30.1 °C (lit.)

溶解性

alcohol: miscible(lit.)
benzene: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble(lit.)

密度

0.641 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES string

CCCC=C

InChI

1S/C5H10/c1-3-5-4-2/h3H,1,4-5H2,2H3

InChI key

YWAKXRMUMFPDSH-UHFFFAOYSA-N

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一般描述

The bacterial mutagenecity of 1-pentene was studied.

应用

1-Pentene was used to develop a rhodium/xantphos homogeneous catalyst system for direct chemo- and regioselective mono-N-alkylation of primary amides with 1-alkenes.

警示用语：

Danger

危险分类

Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-59.8 °F - closed cup

闪点(°C)

-51 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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Saeed Raoufmoghaddam et al.
ChemSusChem, 6(9), 1759-1773 (2013-09-07)
A rhodium/xantphos homogeneous catalyst system has been developed for direct chemo- and regioselective mono-N-alkylation of primary amides with 1-alkenes and syngas through catalytic hydroamidomethylation with 1-pentene and acetamide as model substrates. For appropriate catalyst performance, it appears to be essential
Götz A Westphal et al.
BioMed research international, 2014, 592434-592434 (2014-02-11)
Amylenes are unsaturated hydrocarbons (C5H10), such as 1-pentene, 2-pentene, 2-methyl-but-1-en (3-methyl-1-butene), 2-methyl-but-2-en (isopentene), and 3-methyl-but-1-en. We investigated bacterial mutagenicity of 1-pentene, 2-pentene, and 3-methyl-but-1-en in the Ames test. 2-Pentene was investigated as racemate and as pure diastereomers. We included the
Yu Shan Susanna Wan et al.
Chemical communications (Cambridge, England), (8)(8), 878-879 (2002-07-19)
A zeolite-based microengineered reactor was fabricated and tested for 1-pentene epoxidation over titanium silicalite-1 (TS-1) catalyst, which has been selectively incorporated within the microreactor channel using a new synthesis procedure.
S R Merrigan et al.
Organic letters, 1(2), 327-329 (2000-05-24)
[formula: see text] The 13C and 2H kinetic isotope effects for the bromination of 1-pentene with Br2 in CCl4 were determined and interpreted with the aid of calculationally predicted isotope effects. The isotope effects observed are consistent with rate-limiting bromonium
Takuya Kanemitsu et al.
Organic letters, 5(24), 4541-4544 (2003-11-25)
[reaction: see text] The octenediol linker used during automated oligosaccharide assembly is cleaved by olefin cross-metathesis. Until now, this linker could not be applied to sugars containing azides. A detailed study of the cleavage reaction served as basis for the
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