242489
溴乙腈
97%
别名:
2-溴乙腈, 溴化氰甲基, 溴甲基氰化物
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关于此项目
线性分子式:
BrCH2CN
化学文摘社编号:
分子量:
119.95
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-672-1
Beilstein/REAXYS Number:
956569
MDL number:
产品名称
溴乙腈, 97%
InChI key
REXUYBKPWIPONM-UHFFFAOYSA-N
InChI
1S/C2H2BrN/c3-1-2-4/h1H2
SMILES string
BrCC#N
assay
97%
form
liquid
refractive index
n20/D 1.479 (lit.)
bp
60-62 °C/24 mmHg (lit.)
density
1.722 g/mL at 25 °C (lit.)
functional group
bromo
nitrile
Quality Level
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Application
在 1-氰甲基-1,1-二甲基肼溴化物的合成中使用了溴乙腈 。
General description
溴乙腈是一种有机化合物，通常可用作氰烷基源。 它也可用作有机合成中的化学中间体和烷化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of 4-cyanoethylated benzoxazines by visible-light-promoted radical oxycyanomethylation of olefinic amides with bromoacetonitrile
Sun S, et al.
Tetrahedron Letters, 60(33), 150926-150926 (2019)
Carles Miró Sabaté et al.
Chemistry, an Asian journal, 7(5), 1085-1095 (2012-03-03)
1,1-Dimethylhydrazine can be readily alkylated with bromoacetonitrile to form 1-cyanomethyl-1,1-dimethylhydrazinium bromide ([(CH(3))(2)N(CH(2)CN)NH(2)]Br, 1). The metathesis reaction of compound 1 led to the formation of a new family of energetic salts based on the [(CH(3))(2)N(CH(2)CN)NH(2)](+) cation and nitrate (2), perchlorate (3)
The synthesis of three novel pendant armed macrocyclic ligands. The X-ray crystal structure of a cadmium complex derived from the first oxaazamacrocycle bearing two alkylated aromatic amine functions
Valencia L, et al.
Polyhedron, 20(26-27), 3091-3099 (2001)
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