243272
异氰酸烯丙酯
98%
别名:
3-异氰酰基-1-丙烯
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关于此项目
线性分子式:
CH2=CHCH2NCO
化学文摘社编号:
分子量:
83.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506106
Assay:
98%
Form:
liquid
InChI
1S/C4H5NO/c1-2-3-5-4-6/h2H,1,3H2
SMILES string
C=CCN=C=O
InChI key
HXBPYFMVGFDZFT-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.417 (lit.)
bp
87-89 °C (lit.)
density
0.94 g/mL at 25 °C (lit.)
functional group
amine, isocyanate
storage temp.
2-8°C
Quality Level
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Application
异氰酸烯丙酯用于：
- 与pHPMA的2°羟基反应制备烯丙基-pHPMA（烯丙基-聚N-(2-羟丙基)甲基丙烯酰胺）。
- 通过苯乙烯的双向阴离子聚合反应(bidirectional anionic polymerization)制备含烯丙基的triBCP前体。前体用于合成聚异氰酸烯丙酯-嵌段-聚苯乙烯-嵌段-聚异氰酸烯丙酯(PAIC-b-PSt-b-PAIC)。
General description
臭氧、OH自由基和NO(3)自由基与异氰酸烯丙酯(AIC)气相反应的速率常数已有研究。
异氰酸烯丙酯是一种有机硫化合物，可用于生物可降解葡聚糖-异氰酸烯丙酯-乙胺/聚乙二醇-二丙烯酸水凝胶的合成与鉴定。
异氰酸烯丙酯是一种有机硫化合物，可用于生物可降解葡聚糖-异氰酸烯丙酯-乙胺/聚乙二醇-二丙烯酸水凝胶的合成与鉴定。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of Amphiphilic Helix--Coil--Helix Poly (3-(glycerylthio) propyl isocyanate)-block-polystyrene-block-poly (3-(glycerylthio) propyl isocyanate
Chae CG, et al.
Macromolecules, 51(3), 697-704 (2018)
James K Parker et al.
The journal of physical chemistry. A, 113(36), 9814-9824 (2009-09-04)
Rate constants for the gas-phase reactions of OH radical, NO(3) radical, and ozone with allyl alcohol (AAL) and allyl isocyanate (AIC) have been measured using relative rate methods at atmospheric pressure in purified air. The experimental Arrhenius expression obtained for
Multifunctional poly [N-(2-hydroxypropyl) methacrylamide] copolymers via postpolymerization modification and sequential thiol--ene chemistry
Francini N, et al.
Macromolecules, 48(9), 2857-2863 (2015)
Rui Guo et al.
Journal of applied biomaterials & functional materials, 13(3), e228-e233 (2015-09-10)
This study reports on the synthesis and characterization of biodegradable dextran-allyl isocyanate-ethylamine (Dex-AE)/polyethylene glycol-diacrylate (PEGDA) hydrogels for the controlled release of gentamycin sulphate (GS) and in vitro inhibition of organisms. The Dex-AE precursor was prepared through a 2-step chemical modification
José Miguel Arcas et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 39(6), 949-969 (2018-12-14)
TRPM8 is a polymodal, nonselective cation channel activated by cold temperature and cooling agents that plays a critical role in the detection of environmental cold. We found that TRPM8 is a pharmacological target of tacrolimus (FK506), a macrolide immunosuppressant with
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