243272
异氰酸烯丙酯
98%
别名:
3-异氰酰基-1-丙烯
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关于此项目
线性分子式:
CH2=CHCH2NCO
化学文摘社编号:
分子量:
83.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506106
Assay:
98%
Form:
liquid
InChI
1S/C4H5NO/c1-2-3-5-4-6/h2H,1,3H2
SMILES string
C=CCN=C=O
InChI key
HXBPYFMVGFDZFT-UHFFFAOYSA-N
assay
98%
form
liquid
Quality Level
refractive index
n20/D 1.417 (lit.)
bp
87-89 °C (lit.)
density
0.94 g/mL at 25 °C (lit.)
functional group
amine, isocyanate
storage temp.
2-8°C
General description
臭氧、OH自由基和NO(3)自由基与异氰酸烯丙酯(AIC)气相反应的速率常数已有研究。
异氰酸烯丙酯是一种有机硫化合物，可用于生物可降解葡聚糖-异氰酸烯丙酯-乙胺/聚乙二醇-二丙烯酸水凝胶的合成与鉴定。
异氰酸烯丙酯是一种有机硫化合物，可用于生物可降解葡聚糖-异氰酸烯丙酯-乙胺/聚乙二醇-二丙烯酸水凝胶的合成与鉴定。
Application
异氰酸烯丙酯用于：
- 与pHPMA的2°羟基反应制备烯丙基-pHPMA（烯丙基-聚N-(2-羟丙基)甲基丙烯酰胺）。
- 通过苯乙烯的双向阴离子聚合反应(bidirectional anionic polymerization)制备含烯丙基的triBCP前体。前体用于合成聚异氰酸烯丙酯-嵌段-聚苯乙烯-嵌段-聚异氰酸烯丙酯(PAIC-b-PSt-b-PAIC)。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
European Journal of Organic Chemistry, 2649-2649 (2006)
Synthesis of Amphiphilic Helix--Coil--Helix Poly (3-(glycerylthio) propyl isocyanate)-block-polystyrene-block-poly (3-(glycerylthio) propyl isocyanate
Chae CG, et al.
Macromolecules, 51(3), 697-704 (2018)
Rui Guo et al.
Journal of applied biomaterials & functional materials, 13(3), e228-e233 (2015-09-10)
This study reports on the synthesis and characterization of biodegradable dextran-allyl isocyanate-ethylamine (Dex-AE)/polyethylene glycol-diacrylate (PEGDA) hydrogels for the controlled release of gentamycin sulphate (GS) and in vitro inhibition of organisms. The Dex-AE precursor was prepared through a 2-step chemical modification
Synthesis, characterization of biodegradable dextran--allyl isocyanate--ethylamine/polyethylene glycol--diacrylate hydrogels and their in vitro release of albumin
Sun G and Chu CC
Carbohydrate Polymers, 65(3), 273-287 (2006)
José Miguel Arcas et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 39(6), 949-969 (2018-12-14)
TRPM8 is a polymodal, nonselective cation channel activated by cold temperature and cooling agents that plays a critical role in the detection of environmental cold. We found that TRPM8 is a pharmacological target of tacrolimus (FK506), a macrolide immunosuppressant with
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