248460
三异丙基硅基三氟甲烷磺酸酯
97%
别名:
TIPS三氟甲磺酸酯, 三异丙基甲硅烷基三氟甲烷磺酸盐, 三氟甲烷磺酸三异丙基硅基酯
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关于此项目
线性分子式:
CF3SO3Si[CH(CH3)2]3
化学文摘社编号:
分子量:
306.42
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3591541
Assay:
97%
InChI
1S/C10H21F3O3SSi/c1-7(2)18(8(3)4,9(5)6)16-17(14,15)10(11,12)13/h7-9H,1-6H3
SMILES string
CC(C)[Si](OS(=O)(=O)C(F)(F)F)(C(C)C)C(C)C
InChI key
LHJCZOXMCGQVDQ-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.415 (lit.)
bp
45-46 °C/0.03 mmHg
density
1.14 g/mL at 25 °C (lit.)
functional group
fluoro, triflate
Quality Level
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Application
用于与乙炔锂反应制备甲硅氧基乙炔，甲硅氧基乙炔随后可用于质子酸促进的脂芳烃、炔烃和烯烃的环化反应。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
217.4 °F - closed cup
flash_point_c
103 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis, 74-74 (1991)
Ryunosuke Kuriki et al.
Dalton transactions (Cambridge, England : 2003), 49(35), 12234-12241 (2020-08-28)
New types of diaryloxystannylenes and -plumbylenes have been synthesized and structurally characterized. Lappert's diaminostannylene and -plumbylene E[N(SiMe3)2]2 (E = Sn, Pb) react with 1,3-diethers of tetrathiacalix[4]arene bearing benzyl or SiiPr3 groups to give the corresponding diaryloxystannylenes and -plumbylenes embedded in
Synlett, 435-435 (1993)
Tetrahedron, 62, 11371-11371 (2006)
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