249890
1-溴-2,2-二甲基丙烷
98%
别名:
新戊基溴
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关于此项目
线性分子式:
(CH3)3CCH2Br
化学文摘社编号:
分子量:
151.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-132-5
Beilstein/REAXYS Number:
1730989
MDL number:
产品名称
1-溴-2,2-二甲基丙烷, 98%
InChI key
CQWYAXCOVZKLHY-UHFFFAOYSA-N
InChI
1S/C5H11Br/c1-5(2,3)4-6/h4H2,1-3H3
SMILES string
CC(C)(C)CBr
assay
98%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
105-106 °C/767 mmHg (lit.)
density
1.199 g/mL at 25 °C (lit.)
functional group
alkyl halide
bromo
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
44.6 °F - closed cup
flash_point_c
7 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
An improved method for cysteine alkylation.
Perrey DA and Uckun FM.
Tetrahedron Letters, 42(10), 1859-1861 (2001)
J Ashby et al.
Mutation research, 140(2-3), 71-74 (1984-06-01)
Neopentyl bromide and pentaerythrityl tetrachloride were shown here to be non-mutagenic to 7 strains of Salmonella typhimurium. These inactivities are reflected in the inability of either compound to produce a colour reaction in the chemical alkylation test of Epstein (4-nitrobenzylpyridine
Carmen E Lisowski et al.
The journal of physical chemistry. A, 114(38), 10395-10402 (2010-09-03)
The recombination of chloromethyl and t-butyl radicals at room temperature was used to generate neopentyl chloride molecules with 89 kcal mol(-1) of internal energy. The observed unimolecular reactions, which give 2-methyl-2-butene and 2-methyl-1-butene plus HCl, as products, are explained by
Direct mono-N-alkylation of amines in ionic liquids: chemoselectivity and reactivity.
Chiappe C and Pieraccini D.
Green Chemistry, 5(2), 193-197 (2003)
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