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251682

3-巯基-1-丙磺酸钠

Name: 3-巯基-1-丙磺酸钠
Brand: ALDRICH

technical grade, 90%

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别名:

3-巯基-1-丙烷磺酸钠盐, MPS

线性分子式:

HSCH₂CH₂CH₂SO₃Na

CAS号:

17636-10-1

分子量:

178.21

Beilstein:

5362242

EC 号:

241-620-3

MDL编号:

MFCD00043148

PubChem化学物质编号:

24855149

NACRES:

NA.22

等级

technical grade

检测方案

90%

形式

powder

mp

~220 °C (dec.) (lit.)

溶解性

water: soluble 50 mg/mL, colorless

SMILES string

[Na+].[O-]S(=O)(=O)CCCS

InChI

1S/C3H8O3S2.Na/c4-8(5,6)3-1-2-7;/h7H,1-3H2,(H,4,5,6);/q;+1/p-1

InChI key

FRTIVUOKBXDGPD-UHFFFAOYSA-M

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一般描述

3-巯基-1-丙磺酸钠通过化学吸附在镀金基质上形成自组装单层。

应用

3-巯基-1-丙磺酸钠(MPS)可通过硫醇-烯反应与四乙烯基硅烷发生光化学反应，从而制备四取代有机硅硫醚。它还可以用作封端剂官能化金纳米粒子，有望用于放射治疗和药物递送领域应用。
MPS还可用于通过液相还原氯化铑 (III)制备Rh纳米粒子。

象形图

GHS07

警示用语：

Warning

危险声明

H315 - H319 - H335

预防措施声明

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

159.8 °F - closed cup

闪点(°C)

71 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书(COA)

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示例

T1503

货号

25G

包装规格/数量

其它示例：

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

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Thiol- Ene Reaction for the Synthesis of Multifunctional Branched Organosilanes

Rissing C and Son DY

Organometallics, 27(20), 5394-5397 (2008)

Synthesis of functionalized gold nanoparticles capped with 3-mercapto-1-propansulfonate and 1-thioglucose mixed thiols and ?in vitro? bioresponse

Porcaro F, et al.

Colloids and Surfaces. B, Biointerfaces, 142(20), 408-416 (2016)

Molecular rectification: stabilised alignment of chevron-shaped dyes in hybrid SAM/LB structures in which the self-assembled monolayer is anionic and the Langmuir-Blodgett layer is cationic.

Geoffrey J Ashwell et al.

Faraday discussions, 131, 23-31 (2006-03-04)

The chevron-shaped dye, N-butyl-2,6-bis-[2-{4-(2-(4-dibutylaminophenyl)-vinyl)-phenyl}-vinyl]-pyridinium iodide, has a hydrophilic apex that is electron-accepting and hydrophobic it-bridged limbs that are electron-donating. It forms non-centrosymmetric monolayers at the air-water interface and when deposited, its LB films exhibit second-harmonic generation and asymmetric current-voltage (I-V)

Circulating tumor DNA as an early marker of therapeutic response in patients with metastatic colorectal cancer.

J Tie et al.

Annals of oncology : official journal of the European Society for Medical Oncology, 26(8), 1715-1722 (2015-04-09)

Early indicators of treatment response in metastatic colorectal cancer (mCRC) could conceivably be used to optimize treatment. We explored early changes in circulating tumor DNA (ctDNA) levels as a marker of therapeutic efficacy. This prospective study involved 53 mCRC patients

Hematopoietic cell transplantation for mucopolysaccharidosis patients is safe and effective: results after implementation of international guidelines.

Mieke Aldenhoven et al.

Biology of blood and marrow transplantation : journal of the American Society for Blood and Marrow Transplantation, 21(6), 1106-1109 (2015-02-25)

Allogeneic hematopoietic cell transplantation (HCT) is the only treatment able to prevent progressive neurodegenerative disease in a selected group of mucopolysaccharidosis (MPS) disorders. However, its use was historically limited by the high risk of graft failure and transplantation-related morbidity and

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