CN
所有图片(1)

25170

Sigma-Aldrich

1-(氯甲基)萘

technical, ≥97.0% (GC)

别名:
1-萘甲基氯
线性分子式:
C10H7CH2Cl
CAS号:
分子量:
176.64
Beilstein:
636885
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

等级

technical

测定

≥97.0% (GC)

颜色

deep brown

折射率

n20/D 1.635 (lit.)
n20/D 1.635

bp

167-169 °C/25 mmHg (lit.)

mp

32 °C (lit.)

密度

1.18 g/mL at 25 °C (lit.)

SMILES string

ClCc1cccc2ccccc12

InChI

1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2

InChI key

XMWGTKZEDLCVIG-UHFFFAOYSA-N

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一般描述

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

包装

50 mL in glass bottle

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK Germany

WGK 3

闪点(F)

269.6 °F

闪点(C)

132 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

分析证书

原产地证书 (CofO)

Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)

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