252131
1,5-二碘戊烷
97%, contains copper as stabilizer
别名:
α,ψ-Diiodopentane, (±)-Hexane-1,2-diol, Pentamethylene diiodide
质量水平
方案
97%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.6002 (lit.)
沸点
101-102 °C/3 mmHg (lit.)
密度
2.177 g/mL at 25 °C (lit.)
官能团
iodo
SMILES字符串
ICCCCCI
InChI
1S/C5H10I2/c6-4-2-1-3-5-7/h1-5H2
InChI key
IAEOYUUPFYJXHN-UHFFFAOYSA-N
一般描述
Electrochemical reduction of 1,5-diiodopentane at carbon electrodes in DMF containing tetramethylammonium perchlorate has been studied by cyclic voltammetry and controlled-potential electrolysis.
应用
1,5-Diiodopentane has been used:
- as crosslinking reagent, to investigate the cross-linking layer-by-layer films of bioreducible poly(2-dimethylaminoethyl methacrylate) and DNA
- in preparation of (iodoalkylaminocarbene)tungsten complexes
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Reactions of a-lithio (aminocarbene) tungsten anions with diiodoalkanes: Synthesis of (?-bis (aminocarbene)) ditungsten complexes.
Macomber DW and Madhukar P.
Journal of Organometallic Chemistry, 433(3), 279-285 (1992)
Cross-linked bioreducible layer-by-layer films for increased cell adhesion and transgene expression.
Jenifer Blacklock et al.
The journal of physical chemistry. B, 114(16), 5283-5291 (2010-04-08)
The effect of cross-linking layer-by-layer (LbL) films consisting of bioreducible poly(2-dimethylaminoethyl methacrylate) (rPDMAEMA) and DNA is examined with regard to rigidity, biodegradability, cell adhesion, and transfection activity using 1,5-diiodopentane (DIP) cross-linker. DIP chemically reacts with the tertiary amines of rPDMAEMA
Electrochemical Reduction of 1, 5-Dihalopentanes at Carbon Cathodes in Dimethylformamide.
Pritts WA and Peters DG.
Journal of the Electrochemical Society, 141(12), 3318-3324 (1994)
Ian C Watson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(41), 9678-9690 (2019-05-16)
New N-heterocyclic olefins (NHOs) are described with functionalization on the ligand heterocyclic backbone and terminal alkylidene positions. Various PdII -NHO complexes have been formed and their use as pre-catalysts in Buchwald-Hartwig aminations was explored. The most active system for catalytic
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