253928
1-溴-4-叔丁基苯
97%
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关于此项目
线性分子式:
(CH3)3CC6H4Br
化学文摘社编号:
分子量:
213.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-599-2
Beilstein/REAXYS Number:
1859117
MDL number:
产品名称
1-溴-4-叔丁基苯, 97%
InChI key
XHCAGOVGSDHHNP-UHFFFAOYSA-N
InChI
1S/C10H13Br/c1-10(2,3)8-4-6-9(11)7-5-8/h4-7H,1-3H3
SMILES string
CC(C)(C)c1ccc(Br)cc1
assay
97%
form
liquid
refractive index
n20/D 1.533 (lit.)
bp
80-81 °C/2 mmHg (lit.)
mp
13-16 °C (lit.)
density
1.229 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
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Application
1-溴-4-叔丁基苯用于合成 4-叔丁基苯基硼酸，CP-47,497（n=0 至 7）的 1-脱氧类似物和 Cp-55,940（n=0 至 7）。
General description
在 0°C 下，1-溴-4-叔丁基苯在各种溶剂中与正丁基锂和叔丁基锂进行溴化锂交换反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
206.6 °F
flash_point_c
97 °C
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
Novel non-symmetric nickel-diimine complexes for the homopolymerization of ethene: Control of branching by catalyst design.
Schmid M, et al.
Zeitschrift fur Naturforschung, B: Chemical Sciences, 57(10), 1141-1146 (2002)
William F Bailey et al.
The Journal of organic chemistry, 71(7), 2825-2828 (2006-03-25)
The outcome of reactions of 1-bromo-4-tert-butylbenzene (1), a representative aryl bromide, with n-BuLi or t-BuLi at 0 degrees C in a variety of solvent systems has been investigated. The products of reactions of 1 with n-BuLi vary significantly with changes
John W Huffman et al.
Bioorganic & medicinal chemistry, 16(1), 322-335 (2007-10-09)
A series of 1-deoxy analogs of CP-47,497 (8 and 13, n=0-7) and 1-deoxy analogs of CP-55,940 (9, n=0-7) have been synthesized and their affinities for the cannabinoid CB(1) and CB(2) receptors have been determined. Although the majority of these compounds
Xiao Yan et al.
Physical chemistry chemical physics : PCCP, 22(11), 6222-6230 (2020-03-05)
Unveiling the reaction mechanism is significant for developing high-performance catalysts. In this paper, a series of precisely controlled PdxM147-x (M = Cu, Pt, Au, Rh, Ru) dendrimer encapsulated nanoparticles (DENs) has been successfully synthesized. The mechanisms of PdxM147-x as catalysts
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