254584
巴豆基氯，主要为反式
95%
别名:
1-氯-2-丁烯
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关于此项目
线性分子式:
CH3CH=CHCH2Cl
化学文摘社编号:
分子量:
90.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-516-5
MDL number:
产品名称
巴豆基氯，主要为反式, 95%
InChI key
YTKRILODNOEEPX-NSCUHMNNSA-N
InChI
1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+
SMILES string
[H]\C(C)=C(\[H])CCl
assay
95%
form
liquid
impurities
4% 3-chloro-1-butene
refractive index
n20/D 1.436 (lit.)
bp
84-85 °C (lit.)
density
0.929 g/mL at 25 °C (lit.)
functional group
alkyl halide
chloro
storage temp.
2-8°C
Quality Level
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Application
用巴豆基氯在 298K 下测定了氯原子与一系列不饱和醛酮反应的动力学测量值 。( E ) 巴豆基氯也用于制备 ( E )-丁烯基三氯硅烷。
General description
采用叔胺和铜盐使氯化丁烯与三氯氢硅反应生成相应的的烯丙基三氯氢硅 。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
23.0 °F
flash_point_c
-5 °C
法规信息
危险化学品
此项目有
Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.
Wang W, et al.
Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)
The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.
Furuya N and Sukawa T.
Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)
Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.
Kira M, et al.
Tetrahedron Letters, 30(9), 1099-1102 (1989)
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