260614
3-苯甲酰基丙烯酸乙酯
technical grade, 92%
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线性分子式:
C6H5COCH=CHCO2C2H5
化学文摘社编号:
分子量:
204.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
3-苯甲酰基丙烯酸乙酯, technical grade, 92%
InChI
1S/C12H12O3/c1-2-15-12(14)9-8-11(13)10-6-4-3-5-7-10/h3-9H,2H2,1H3/b9-8+
SMILES string
CCOC(=O)\C=C\C(=O)c1ccccc1
InChI key
ACXLBHHUHSJENU-CMDGGOBGSA-N
grade
technical grade
assay
92%
form
liquid
refractive index
n20/D 1.543 (lit.)
bp
184-185 °C/25 mmHg (lit.)
density
1.112 g/mL at 25 °C (lit.)
Quality Level
General description
3-苯甲酰基丙烯酸乙酯（反式-3-苯甲酰基丙烯酸乙酯）经对映选择性胍催化剂促进与地蒽酚的Michael加成反应生成Michael加合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Juan Shen et al.
Organic & biomolecular chemistry, 6(18), 3229-3236 (2008-09-20)
The enantioselective Diels-Alder reaction is one of the most important reactions for the synthesis of complex molecules. It provides access to chiral six-membered carbocyclic compounds containing up to four stereogenic centers in a single step. Asymmetric catalysis in the Diels-Alder
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