产品名称
三环己基膦,
form
solid
Quality Level
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Hiyama Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
81-83 °C (lit.)
functional group
phosphine
SMILES string
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InChI
1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
InChI key
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Application
用于丙二腈与芳基卤化物的钯催化偶联反应的配体。大位阻膦配体，与 Pd(0)-三烯酸大环催化剂一起用于芳基溴化物和氯化物的 Suzuki 偶联反应。
该配体与镍可用作形成环戊烷化合物的关键中间体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
相关内容
Phosphine Ligand Application Guide
Sensuke Ogoshi et al.
Journal of the American Chemical Society, 128(16), 5350-5351 (2006-04-20)
Cyclopropyl phenyl ketone underwent oxidative addition to Ni(PCy3) generated from Ni(cod)2 and PCy3 to give a nickeladihydropyran, which is a key intermediate for the Ni(0)-catalyzed homo- or heterocycloaddition to give cyclopentane compounds having two carbonyl substituents at the 1,3-position.
Synlett, 3167-3167 (2006)
Synlett, 3001-3001 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 261971-250G | 04061833398173 |
| 261971-5G | 04061826107904 |
| 261971-25G | 04061826107881 |
| 261971-1G | 04061826107850 |