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Merck
CN

262242

对苯二异氰酸酯

别名:

1,4-二异氰酸苯酯, 对苯二异氰酸酯

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关于此项目

线性分子式:
C6H4(NCO)2
化学文摘社编号:
分子量:
160.13
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽压

<0.01 mmHg ( 20 °C)

表单

solid

沸点

260 °C (lit.)

mp

96-99 °C (lit.)

溶解性

THF: soluble
acetone: soluble
ethyl acetate: soluble
toluene: soluble

官能团

isocyanate

SMILES字符串

O=C=Nc1ccc(cc1)N=C=O

InChI

1S/C8H4N2O2/c11-5-9-7-1-2-8(4-3-7)10-6-12/h1-4H

InChI key

ALQLPWJFHRMHIU-UHFFFAOYSA-N

应用

1,4-苯二异氰酸酯(PPDI)可用作:
  • 一种通过与烷基叠氮在吡啶中的交叉加成聚合反应合成高产聚合物的反应物。
  • 一种制备含金刚烷基的二脲和硫脲衍生物的有机构建块,可作为强效哺乳动物和人类可溶性环氧化物水解酶抑制剂。
  • 一种以二月桂酸二丁基锡(DBTDL)为催化剂合成聚乙二醇(PEG)/二氧化硅复合材料的偶联剂。

它也可用于:
  • 作为交联剂,研究硅烷化表面固定化酶的机理。
  • 在偶极双脲受体的合成中,这是一种硫酸氢的选择性受体。
  • 在聚脲抗蚀膜的沉积中,通过分子层沉积。

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Aquatic Chronic 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

>235.4 °F - closed cup

闪点(°C)

> 113 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polymer, 50(10), 2246-2251 (2009)
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Advanced materials (Deerfield Beach, Fla.), 31(4), e1806541-e1806541 (2018-12-06)
Metallic Li is considered as one of the most promising anode materials for next-generation batteries due to its high theoretical capacity and low electrochemical potential. However, its commercialization has been impeded by the severe safety issues associated with Li-dendrite growth.
Mahbobeh Ghazagh Miri et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 205, 200-206 (2018-07-18)
A 3D urea-based porous organic polymer (Urea-POP) was prepared via the reaction of tetrakis(4-aminophenyl)methane and 1,4-Phenylene diisocyanate. The polymer was subsequently reacted with 2D layered nanosheets of graphene oxide (GO) to prepare Urea-POP/GO as a novel and highly efficient sorbent
S K Dogan et al.
Journal of the mechanical behavior of biomedical materials, 71, 349-361 (2017-04-14)
Poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends were melt-mixed and compatibilized to investigate their biocompatibility, biodegradability and thermally induced shape memory properties. The blend compositions were PLA/TPU: 80/20 (20TPU) and PLA/TPU: 50/50 (50TPU). 1,4-phenylene diisocyanate (PDI) was used in order to
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