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268062

D-哌啶酸

Name: <SC>D</SC>-哌啶酸
Brand: ALDRICH

99%

别名:

(R)-(+)-2-哌啶甲酸, (R)-哌啶-2-羧酸, D-高脯氨酸

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关于此项目

经验公式（希尔记法）:

C₆H₁₁NO₂

化学文摘社编号:

1723-00-8

分子量:

129.16

UNSPSC Code:

12352209

NACRES:

NA.22

PubChem Substance ID:

24856260

EC Number:

217-024-4

Beilstein/REAXYS Number:

81094

MDL number:

MFCD00064346

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属性

assay

99%

optical activity

[α]25/D +27°, c = 1 in H₂O

reaction suitability

reaction type: solution phase peptide synthesis

mp

277 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

OC(=O)[C@H]1CCCCN1

InChI

1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m1/s1

InChI key

HXEACLLIILLPRG-RXMQYKEDSA-N

说明

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Enantioselective allylation of imines catalyzed by newly developed (-)-β-pinene-based π-allylpalladium catalyst: an efficient synthesis of (R)-α-propylpiperonylamine and (R)-pipecolic acid.

Rodney A Fernandes et al.

Organic & biomolecular chemistry, 10(38), 7789-7800 (2012-08-23)

A newly developed π-allylpalladium with a (-)-β-pinene framework and an isobutyl side chain catalyzed the enantioselective allylation of imines in good yields and enantioselectivities (20 examples, up to 98% ee). An efficient enantioselective synthesis of the (R)-α-propyl piperonylamine part of

Pipecolic acid, an endogenous mediator of defense amplification and priming, is a critical regulator of inducible plant immunity.

Hana Návarová et al.

The Plant cell, 24(12), 5123-5141 (2012-12-12)

Metabolic signals orchestrate plant defenses against microbial pathogen invasion. Here, we report the identification of the non-protein amino acid pipecolic acid (Pip), a common Lys catabolite in plants and animals, as a critical regulator of inducible plant immunity. Following pathogen

Modulating D-amino acid oxidase (DAAO) substrate specificity through facilitated solvent access.

Kalyanasundaram Subramanian et al.

PloS one, 13(6), e0198990-e0198990 (2018-06-16)

D-amino acid oxidase (DAAO) degrades D-amino acids to produce α-ketoacids, hydrogen peroxide and ammonia. DAAO has often been investigated and engineered for industrial and clinical applications. We combined information from literature with a detailed analysis of the structure to engineer

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全球贸易项目编号

货号	GTIN
268062-100MG	04061833279076