271411
烯丙基三丁基锡
97%
别名:
Allyltri-n-butyltin, Allyltributyltin, Tributyl-2-propenylstannane
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关于此项目
线性分子式:
CH2=CHCH2Sn(CH2CH2CH2CH3)3
化学文摘社编号:
分子量:
331.12
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
246-494-3
Beilstein/REAXYS Number:
3588340
MDL number:
Assay:
97%
Form:
liquid
Quality Segment
assay
97%
form
liquid
refractive index
n20/D 1.486 (lit.)
bp
88-92 °C/0.2 mmHg (lit.)
density
1.068 g/mL at 25 °C (lit.)
SMILES string
CCCC[Sn](CCCC)(CCCC)CC=C
InChI
1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;
InChI key
YLGRTLMDMVAFNI-UHFFFAOYSA-N
Application
醛的烯丙基化试剂，该反应的催化剂为手性路易斯酸和三氟甲烷磺酸镱(III)（产品号430595）。在四(三苯基膦)钯(0)（产品号216666）催化下，与碘醌和乙酸烯丙酯发生偶联反应。
用于醛与三氯-1,3,5-三氮烯的高效烯丙基化反应，生成高烯丙醇。
用于醛与三氯-1,3,5-三氮烯的高效烯丙基化反应，生成高烯丙醇。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
217.4 °F - closed cup
flash_point_c
103 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter