assay
98%
form
solid
optical activity
[α]20/D +200°, c = 2 in acetone
mp
104-106 °C (lit.)
functional group
sulfinic acid
storage temp.
2-8°C
SMILES string
C[C@H]1CC[C@H](C(C)C)[C@H](C1)OS(=O)c2ccc(C)cc2
InChI
1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m0/s1
InChI key
NQICGNSARVCSGJ-DZIWXPPMSA-N
Application
(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:
- As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
- To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
- In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)