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安全信息

279897

Sigma-Aldrich

(R)-(-)-2-苯基丙酸

97%

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别名:
(R)-(-)-氢化阿托酸, (R)-HTA
线性分子式:
CH3CH(C6H5)CO2H
CAS号:
7782-26-5
分子量:
150.17
Beilstein:
2207688
MDL编号:
MFCD00063140
PubChem化学物质编号:
24856914
NACRES:
NA.22

检测方案

97%

形式

solid

旋光性

[α]20/D −72°, c = 1.6 in chloroform

光学纯度

ee: 98% (HPLC)

折射率

n20/D 1.523 (lit.)

bp

115 °C/1 mmHg (lit.)

mp

29-30 °C (lit.)

密度

1.1 g/mL at 25 °C (lit.)

SMILES string

C[C@@H](C(O)=O)c1ccccc1

InChI

1S/C9H10O2/c1-7(9(10)11)8-5-3-2-4-6-8/h2-7H,1H3,(H,10,11)/t7-/m1/s1

InChI key

YPGCWEMNNLXISK-SSDOTTSWSA-N

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相关类别

应用

手性结构单元。拆分剂

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319 - H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Y Tanaka et al.
Chirality, 4(6), 342-348 (1992-01-01)
It has been proposed that the chiral inversion of the 2-arylpropionic acids is due to the stereospecific formation of the (-)-R-profenyl-CoA thioesters which are putative intermediates in the inversion. Accordingly, amino acid conjugation, for which the CoA thioesters are obligate
David M Shackleford et al.
Journal of pharmacokinetics and pharmacodynamics, 31(1), 1-27 (2004-09-07)
Numerous studies have previously been conducted with the impulse-response isolated perfused rat liver (IR-IPRL) to establish the role of both physiological and physicochemical factors in determining solutes' pattern of hepatic disposition, however the impact of optical isomerism on hepatic disposition
Chunze Li et al.
Chemical research in toxicology, 15(11), 1480-1487 (2002-11-20)
A series of studies was conducted to investigate the potential of (R)- and (S)-2-phenylpropionic acid (2-PPA) to undergo enantioselective covalent binding to protein in freshly isolated rat hepatocytes and to determine whether such covalent binding is dependent on acyl glucuronidation
D Ahmad et al.
Chirality, 6(5), 365-371 (1994-01-01)
The significance of disturbances of lipid metabolism caused by xenobiotic acyl-CoAs as possible causes of peroxisomal proliferation has been studied with the enantiomers of 2-phenylpropionic acid (2-PPA), the (R)-enantiomer of which is converted to the acyl-CoA in rats while its
Chunze Li et al.
Chemical research in toxicology, 15(10), 1309-1317 (2002-10-22)
Chemically reactive species formed from the metabolism of carboxylic acid-containing compounds have been proposed as mediators of their toxic side-effects. Two alternative metabolic pathways known to be involved in the generation of reactive acylating metabolites of carboxylic acids are acyl
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Chromatograms

application for HPLC

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