280097
3-溴碘苯
98%
别名:
1-Bromo-3-iodobenzene, 1-Iodo-3-bromobenzene, 3-Bromo-1-iodobenzene, 3-Bromophenyl iodide, 3-Iodo-1-bromobenzene, 3-Iodobromobenzene, 3-Iodophenyl bromide, m-Bromoiodobenzene
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关于此项目
线性分子式:
BrC6H4I
化学文摘社编号:
分子量:
282.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-703-9
MDL number:
产品名称
3-溴碘苯, 98%
InChI key
CTPUUDQIXKUAMO-UHFFFAOYSA-N
InChI
1S/C6H4BrI/c7-5-2-1-3-6(8)4-5/h1-4H
SMILES string
Brc1cccc(I)c1
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.66 (lit.)
bp
120 °C/18 mmHg (lit.)
mp
−9.3-−9 °C (lit.)
density
2.219 g/mL at 25 °C (lit.)
functional group
bromo
iodo
Quality Level
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Application
3-Bromoiodobenzene has been used in the preparation of:
- 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene
- 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
- oxygen-tethered 1,6-enynes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Alexandre Pradal et al.
Beilstein journal of organic chemistry, 7, 1021-1029 (2011-09-15)
A comprehensive study on the asymmetric gold-catalyzed cycloisomerization reaction of heteroatom tethered 1,6-enynes is described. The cycloisomerization reactions were conducted in the presence of the chiral cationic Au(I) catalyst consisting of (R)-4-MeO-3,5-(t-Bu)(2)-MeOBIPHEP-(AuCl)(2) complex and silver salts (AgOTf or AgNTf(2)) in
Efficient access to perfluoroalkylated aryl compounds by Heck reaction.
Darses S, et al.
European Journal of Organic Chemistry, 2001(6), 1121-1128 (2001)
Junpei Miyake et al.
Science advances, 3(10), eaao0476-eaao0476 (2017-10-28)
Proton exchange membrane fuel cells (PEMFCs) are promising devices for clean power generation in automotive, stationary, and portable applications. Perfluorosulfonic acid (PFSA) ionomers (for example, Nafion) have been the benchmark PEMs; however, several problems, including high gas permeability, low thermal
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