282855
3-甲基-2,4-戊二酮（互变异构体混合物）
technical grade, 85%
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关于此项目
线性分子式:
CH3COCH(CH3)COCH3
化学文摘社编号:
分子量:
114.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
212-420-3
MDL number:
Assay:
85%
Form:
liquid
grade
technical grade
Quality Level
assay
85%
form
liquid
refractive index
n20/D 1.442 (lit.)
bp
172-174 °C (lit.)
density
0.981 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
CC(C(C)=O)C(C)=O
InChI
1S/C6H10O2/c1-4(5(2)7)6(3)8/h4H,1-3H3
InChI key
GSOHKPVFCOWKPU-UHFFFAOYSA-N
General description
据报道，过氧亚硝酸盐促进 3-甲基-2,4-戊二酮的好氧氧化。在气相中使用脉冲激光光解-激光诱导荧光技术研究了 OH 自由基与 3-甲基-2,4-戊二酮的反应动力学。3-甲基-2,4-戊二酮参与两亲树脂负载的单齿膦配体催化的 1,3-二苯基-2-丙烯基乙酸酯的不对称取代。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
134.6 °F - closed cup
flash_point_c
57 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Palladium-catalyzed asymmetric allylic substitution in aqueous media using amphiphilic resin-supported MOP ligands.
Uozumi Y, et al.
Tetrahedron Letters, 39(45), 8303-8306 (1998)
Jiyuan Jin et al.
Chemosphere, 223, 628-635 (2019-02-25)
Quinones are components of electron transport chains in photosynthesis and respiration. Acetylacetone (AA), structurally similar to benzoquinone (BQ) for the presence of two identical carbonyl groups, has been reported as a quinone-like electron shuttle. Both BQ and AA are important
Rate coefficients for the reactions of OH radicals with the keto/enol tautomers of 2, 4-pentanedione and 3-methyl-2, 4-pentanedione, allyl alcohol and methyl vinyl ketone using the enols and methyl nitrite as photolytic sources of OH.
Holloway A-L, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 176(1), 183-190 (2005)
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| 货号 | GTIN |
|---|---|
| 282855-25G | 04061836683832 |