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287059

L-脯氨酰胺

Name: <SC>L</SC>-脯氨酰胺
Brand: ALDRICH

98%, for peptide synthesis

别名:

(2S)-2-Carbamoylpyrrolidine

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关于此项目

经验公式（希尔记法）:

C₅H₁₀N₂O

化学文摘社编号:

7531-52-4

分子量:

114.15

NACRES:

NA.22

PubChem Substance ID:

24857262

UNSPSC Code:

12352209

EC Number:

231-397-0

MDL number:

MFCD00005253

Beilstein/REAXYS Number:

80807

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属性

产品名称

L-脯氨酰胺, 98%

Quality Level

100

assay

98%

optical activity

[α]20/D −106°, c = 1 in ethanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

95-97 °C (lit.)

application(s)

peptide synthesis

SMILES string

NC(=O)[C@@H]1CCCN1

InChI

1S/C5H10N2O/c6-5(8)4-2-1-3-7-4/h4,7H,1-3H2,(H2,6,8)/t4-/m0/s1

InChI key

VLJNHYLEOZPXFW-BYPYZUCNSA-N

说明

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chirally functionalized hollow nanospheres containing L-prolinamide: synthesis and asymmetric catalysis.

Jinsuo Gao et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 16(26), 7852-7858 (2010-05-29)

Chirally functionalized hollow nanospheres with different surface properties were successfully synthesized by co-condensation of (2S,1'R,2'R)-N-tert-butyloxycarbonylpyrrolidine-2-carboxylic acid [2'-(4-trimethoxysilylbenzylamide)cyclohexyl] amide with 1,2-bis(trimethoxysilyl)ethane or tetramethoxysilane using F127 (EO(106)PO(70)EO(106)) as surfactant in water. The TEM and N(2) sorption characterizations show that the particle size

A tripeptide-like prolinamide-thiourea as an aldol reaction catalyst.

Stamatis Fotaras et al.

Organic & biomolecular chemistry, 10(29), 5613-5619 (2012-06-22)

A tripeptide-like prolinamide-thiourea catalyst with (S)-proline, (1S,2S)-diphenylethylenediamine and (S)-di-tert-butyl aspartate as building blocks provides the products of the reaction between ketones and aromatic aldehydes in high to quantitative yields and high stereoselectivities (up to 99:1 dr and 99% ee). Both

Readily tunable and bifunctional L-prolinamide derivatives: design and application in the direct enantioselective Aldol reactions.

Jia-Rong Chen et al.

Organic letters, 7(20), 4543-4545 (2005-09-24)

[reaction: see text] Readily tunable and bifunctional L-prolinamides as novel organocatalysts have been developed, and their catalytic activities were evaluated in the direct asymmetric Aldol reactions of various aromatic aldehydes and cyclohexanone. High isolated yields (up to 94%), enantioselectivities (up

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全球贸易项目编号

货号	GTIN
287059-1G	04061826265925
287059-5G	04061826265932