294632
二甲氧基乙酸甲酯
97%
别名:
2,2-二甲氧基乙酸甲酯
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关于此项目
线性分子式:
(CH3O)2CHCOOCH3
化学文摘社编号:
分子量:
134.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-950-0
Beilstein/REAXYS Number:
1757582
MDL number:
Assay:
97%
InChI key
NZTCVGHPDWAALP-UHFFFAOYSA-N
InChI
1S/C5H10O4/c1-7-4(6)5(8-2)9-3/h5H,1-3H3
SMILES string
COC(OC)C(=O)OC
assay
97%
refractive index
n20/D 1.405 (lit.)
bp
67 °C/18 mmHg (lit.)
density
1.096 g/mL at 25 °C (lit.)
functional group
acetal, ester, ether
storage temp.
2-8°C
Quality Level
Application
Methyl dimethoxyacetate has been used:
- in Claisen acylation of active hydrogen compounds
- in preparation of 3, 9-disubstituted 2,4,8,10-tetroxaspiro [5.5] undecane
- as Lithium enolate precursor
- as acylating reagent for cycloalkanone enolates and amino alcohols
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
152.6 °F - closed cup
flash_point_c
67 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Studies in Mixed Ester Condensations. IV. Acylations with Methyl Dimethoxyacetate1.
Royals EE and Robinson AG.
Journal of the American Chemical Society, 78(16), 4161-4164 (1956)
Tetrahedron, 46, 6799-6799 (1990)
Some 3, 9-Dicarboxylic Acids of 2, 4, 8, 10-Tetroxaspiro [5.5] undecane.
CLEMENTS JB and RICE LM.
The Journal of Organic Chemistry, 24(12), 1958-1961 (1959)
Synthetic Communications, 23, 1003-1003 (1993)
P J Connolly et al.
Journal of medicinal chemistry, 36(23), 3674-3685 (1993-11-12)
Compounds comprising a series of 7-[2-(4-fluorophenyl)-4,5,6,7-tetrahydro-2H-indazol-3-yl]-3,5- dihydroxy-6-heptenoic acid sodium salts (18) were synthesized and tested for their ability to inhibit HMG-CoA reductase in a partially purified enzyme preparation and cholesterol biosynthesis from acetate in cultured HEP-G2 cells. Changing the size
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