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Merck
CN

295086

反式-2-丁烯

≥99%

别名:

β-反式丁烯, (2E)-2-丁烯, (E)-2-丁烯, 2-trans-丁烯, 2-反式丁烯, E-丁烯, 反丁烯, 反式-1,2-二甲基乙烯, 反式-2-丁烯

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关于此项目

线性分子式:
CH3CH=CHCH3
化学文摘社编号:
分子量:
56.11
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-855-3
Beilstein/REAXYS Number:
1718756
MDL number:
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产品名称

反式-2-丁烯, ≥99%

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

SMILES string

CC=CC

vapor density

2 (vs air)

vapor pressure

2575 mmHg ( 37.7 °C)

assay

≥99%

autoignition temp.

615 °F

expl. lim.

9.7 %

bp

1 °C (lit.)

mp

−105 °C (lit.)

Quality Level

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Application

反式-2-丁烯可用作单体单元,通过镍催化聚合反应产生具有既定微观结构的高分子量聚烯烃。也可用作异构化反应中的反应物,使用酸活化催化剂产生对应异构体。

Packaging

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。在使用气瓶前,务必确保阀门是关闭的,然后取下密封出口阀的镀锌钢六角螺帽。

兼容以下设备:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

pictograms

FlameGas cylinder

signalword

Danger

hcodes

Hazard Classifications

Flam. Gas 1 - Press. Gas Liquefied gas

存储类别

2A - Gases

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ni (II)-catalyzed polymerization of trans-2-butene
Leatherman MD and Brookhart M
Macromolecules, 34(9), 2748-2750 (2001)
Isomerization of cis-2-butene and trans-2-butene catalyzed by acid-and ion-exchanged smectite-type clays
Moronta A, et al.
Applied Clay Science, 29(2), 117-123 (2005)
Duangkamol Gleeson
Journal of computer-aided molecular design, 22(8), 579-585 (2008-03-18)
In this study the results from a series of calculations are reported that probe the influence of the QM cluster size and the extended framework treatment in ONIOM calculations. This is done by comparing the differences in the structures and
Philip T M Carlsson et al.
Physical chemistry chemical physics : PCCP, 14(45), 15637-15640 (2012-10-24)
Recent studies have suggested that the reaction of stabilised Criegee Intermediates (CIs) with sulfur dioxide (SO(2)), leading to the formation of a carbonyl compound and sulfur trioxide, is a relevant atmospheric source of sulfuric acid. Here, the significance of this
Franz Worek et al.
Archives of toxicology, 86(9), 1379-1386 (2012-03-23)
The reactivation of organophosphorus compound (OP)-inhibited acetylcholinesterase (AChE) by oximes is inadequate in case of different OP nerve agents. This fact led to the synthesis of numerous novel oximes by different research groups in order to identify more effective reactivators.

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