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Merck
CN

295116

一氧化碳

≥99.0%

别名:

一氧化碳(CO)

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关于此项目

经验公式(希尔记法):
CO
化学文摘社编号:
分子量:
28.01
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-128-3
Beilstein/REAXYS Number:
3587264
MDL number:
Assay:
≥99.0%
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InChI key

UGFAIRIUMAVXCW-UHFFFAOYSA-N

InChI

1S/CO/c1-2

SMILES string

[C-]#[O+]

vapor density

0.97 (vs air)

assay

≥99.0%

autoignition temp.

1128 °F

expl. lim.

74 %

bp

−191.5 °C (lit.)

mp

−205 °C (lit.)

Quality Level

General description

一氧化碳是一种多用途合成砌块,广泛用于羰基化反应和制备单壁碳纳米管。

Application

一氧化碳有下列用途:
  • 过渡金属催化羰基化反应。
  • 在共聚反应中一氧化碳插入金属-碳键。
  • 利用钼粒子催化歧化反应生长单壁碳纳米管。

在过渡金属催化剂上催化氢化一氧化碳以形成烃已有报道。

Packaging

提供安装了 CGA180M/CGA110F 针阀的碳钢气阀瓶。

与以下产品兼容:
  • Aldrich® 气阀瓶站系统
  • Aldrich® 气阀瓶气体调节器

Other Notes

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Flam. Gas 1A - Press. Gas Compr. Gas - Repr. 1A - STOT RE 1 Inhalation

target_organs

Heart

存储类别

2A - Gases

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide.
Drent E, et al.
Chemical Reviews, 96(2), 663-682 (1996)
Single-wall nanotubes produced by metal-catalyzed disproportionation of carbon monoxide.
Dai H, et al.
Chemical Physics Letters, 260(3-4), 471-475 (1996)
Insertion of carbon monoxide and alkenes in palladium-carbon bonds of complexes containing rigid bidentate nitrogen ligands: the first example of isolated complexes in stepwise successive insertion reactions on the way to polyketones.
Asselt V, et al.
Journal of the American Chemical Society, 116, 977-977 (1994)
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