295469
2-甲基丙烯
99%
别名:
异丁烯
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关于此项目
线性分子式:
(CH3)2C=CH2
化学文摘社编号:
分子量:
56.11
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-066-3
Beilstein/REAXYS Number:
773645
MDL number:
Assay:
99%
Application
3-甲基丙烯可用于以下反应：
- 不对称合成 S-（+）-2，2-二甲基环丙烷羧酸，是西司他丁合成的关键组成部分。
- 杂多酸催化对-二甲苯烷基化形成叔-丁基-对-二甲苯。
- 聚（2-甲基丙烯）或聚异丁烯的合成。
General description
2-甲基丙烯用于通过不对称环丙烷化反应合成S-(+)-2,2-二甲基环丙烷羧酸。
Packaging
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Gas 1 - Press. Gas Liquefied gas
存储类别
2A - Gases
wgk
nwg
flash_point_f
-112.0 °F - closed cup
flash_point_c
-80 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
监管及禁止进口产品
此项目有
Selective alkylation of p-xylene with 2-methylpropene by 12-tungstophosphoric acid.
Soeda H, et al.
Chemistry Letters (Jpn), 23(5), 909-912 (1994)
The synthesis of S-(+)-2, 2-dimethylcyclopropane carboxylic acid: a precursor for cilastatin.
Wang Q, et al.
Tetrahedron Asymmetry, 9(22), 3971-3977 (1998)
Molybdenum (III) Compounds as Catalysts for 2?Methylpropene Polymerization.
Hijazi A K, et al.
Angewandte Chemie (International Edition in English), 46(38), 7290-7292 (2007)
The synthesis of S-(+)-2, 2-dimethylcyclopropane carboxylic acid: a precursor for cilastatin
Wang Q, et al.
Tetrahedron Asymmetry, 9, 3971-3977 (1998)
Hongfu Yuan et al.
Applied spectroscopy, 61(1), 96-101 (2007-02-22)
The molar ratio between methanol and isobutylene (MRMI) is very important to the operation of methyl tertiary butyl ether (MTBE) production units. A new on-line near-infrared (NIR) analytical system was integrated for monitoring the MRMI in real time and was
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