一般描述
丙烯是一种非极性烯烃。它通常用作合成异丙基苯、环氧丙烷、丙烯腈和异丙醇的前体。研究人员已经报道过Au/TiO2 催化剂作用下含氧和氢气体中丙烯的选择性氧化。研究人员已经研究过以齐格勒-纳塔催化剂进行丙烯的聚合。研究人员已经提及金属催化的非极性烯烃（乙烯和丙烯）与烷基丙烯酸酯的共聚合。研究人员已经研究过丙烯与线性α-烯烃1-辛烯、1-癸烯、1-十四碳烯和1-十八碳烯的共聚合。
应用
在钛硅沸石催化剂存在下，丙烯可用于通过用过氧化氢环氧化合成环氧丙烷。
包装
法律信息
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险声明
预防措施声明
危险分类
Flam. Gas 1 - Press. Gas Liquefied gas
储存分类代码
2A - Gases
WGK
WGK 3
闪点(°F)
-162.4 °F - closed cup
闪点(°C)
-108 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
监管及禁止进口产品
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Lei Ma et al.
Environmental science & technology, 46(3), 1747-1754 (2012-01-14)
Application of Fe-zeolites for urea-SCR of NO(x) in diesel engine is limited by catalyst deactivation with hydrocarbons (HCs). In this work, a series of Fe-zeolite catalysts (Fe-MOR, Fe-ZSM-5, and Fe-BEA) was prepared by ion exchange method, and their catalytic activity
Manab Sharma et al.
Journal of the American Chemical Society, 134(41), 17234-17244 (2012-09-21)
The use of bis(1,3-di-tert-butylimidazolin-2-iminato) titanium dichloride (1) and dimethyl (2) complexes in the polymerization of propylene is presented. The complexes were activated using different amounts of methylalumoxane (MAO), giving in each case a very active catalytic mixture and producing polymers
Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite.
Clerici MG, et al.
J. Catal., 129(1), 159-167 (1991)
Thomas Hampel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(33), 10382-10392 (2012-07-19)
The title compounds were synthesized in a longest sequence of 27 linear steps and with an overall yield of 2.9 and 3.9%. In the course of the synthesis, two aldehydes representing carbon fragments C1-C7 (Eastern fragment) and C9-C21 (Western fragment)
Christian Schäfer et al.
Organic & biomolecular chemistry, 10(16), 3253-3257 (2012-03-13)
Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (η(2)-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly fused unsaturated tricyclic lactones which represent relevant substructures of numerous bioactive compounds.
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