298212
硫氰酸亚铜
99%
别名:
硫氰化亚铜
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关于此项目
线性分子式:
CuSCN
化学文摘社编号:
分子量:
121.63
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
214-183-1
MDL number:
Assay:
99%
Form:
powder
产品名称
硫氰酸亚铜, 99%
InChI key
PDZKZMQQDCHTNF-UHFFFAOYSA-M
InChI
1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1
SMILES string
[Cu]SC#N
assay
99%
form
powder
reaction suitability
core: copper
Quality Level
Application
本品可Cu(CH3COO)2·H2O、AgNO3、NH4NCS和im(im = 咪唑)制备。本品的结构和光学性质已被报道。 它是一种空气和光稳定的Cu（I）源。
General description
其晶体属于斜方晶系，空间群：Pbca,a=10.994(9)Å, b=7.224(3)Å,c=6.662(2)Å.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
supp_hazards
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
The crystal structure of copper(I) thiocyanate and its relation to the crystal structure of copper(II) diammine dithiocyanate complex
Kabesova M, et al.
Inorgorganica Chimica Acta, 17, 161-165 (1976)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 41(25), 7513-7525 (2012-05-24)
A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), (39)(39), 5290-5292 (2008-10-02)
The role of short-range diffusion in solvent-assisted mechanochemical synthesis is demonstrated in studies of a polymorphic transition and a ligand dissociation reaction involving copper(I) thiocyanate complexes.
S Bacon
Journal of human nutrition, 34(6), 445-449 (1980-12-01)
The advantages and disadvantages of faecal markers that are available in the UK are discussed. Opinions and comments from units using them are included.
Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound
Bie HY, et al.
Journal of Molecular Structure, 660, 107-112 (2003)
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