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298212

硫氰酸亚铜

Name: 硫氰酸亚铜
Brand: ALDRICH

99%

别名:

硫氰化亚铜

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关于此项目

线性分子式:

CuSCN

化学文摘社编号:

1111-67-7

分子量:

121.63

NACRES:

NA.23

PubChem Substance ID:

24857968

UNSPSC Code:

12352302

EC Number:

214-183-1

MDL number:

MFCD00010980

Assay:

99%

Form:

powder

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属性

Quality Level

100

assay

99%

form

powder

reaction suitability

core: copper

SMILES string

[Cu]SC#N

InChI

1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1

InChI key

PDZKZMQQDCHTNF-UHFFFAOYSA-M

说明

General description

其晶体属于斜方晶系，空间群：Pbca,a=10.994(9)Å, b=7.224(3)Å,c=6.662(2)Å.

Application

本品可Cu(CH₃COO)₂·H₂O、AgNO₃、NH₄NCS和im(im = 咪唑)制备。本品的结构和光学性质已被报道。它是一种空气和光稳定的Cu（I）源。

pictograms

GHS09

signalword

Warning

hcodes

H410

pcodes

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

supp_hazards

EUH032

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The crystal structure of copper(I) thiocyanate and its relation to the crystal structure of copper(II) diammine dithiocyanate complex

Kabesova M, et al.

Inorgorganica Chimica Acta, 17, 161-165 (1976)

Mechanochemical and solution synthesis, X-ray structure and IR and 31P solid state NMR spectroscopic studies of copper(I) thiocyanate adducts with bulky monodentate tertiary phosphine ligands.

Graham A Bowmaker et al.

Dalton transactions (Cambridge, England : 2003), 41(25), 7513-7525 (2012-05-24)

A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a

The role of short-range diffusion in solvent-assisted mechanochemical synthesis of metal complexes.