Merck
CN

301884

Sigma-Aldrich

苯基-2-吡啶基酮肟

98%

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经验公式(希尔记法):
C12H10N2O
CAS号:
分子量:
198.22
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

检测方案

98%

形式

powder

mp

154-156 °C (lit.)

SMILES string

O\N=C(/c1ccccc1)c2ccccn2

InChI

1S/C12H10N2O/c15-14-12(10-6-2-1-3-7-10)11-8-4-5-9-13-11/h1-9,15H/b14-12+

InChI key

RSJDEVMJZLLAHS-WYMLVPIESA-N

一般描述

The complexation reaction of phenyl 2-pyridyl ketoxime with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La2+ has been studied potentiometrically. The reactions of phenyl(2-pyridyl)ketone oxime, with nickel(II) sulfate hexahydrate, in the absence of an external base, have been investigated.

应用

Phenyl 2-pyridyl ketoxime was used in preparation of inverse-9-metallacrown-3, trinuclear clusters.

质量

可能具有顺式和反式构型

象形图

CorrosionSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Tereza Afrati et al.
Dalton transactions (Cambridge, England : 2003), 39(3), 765-775 (2010-01-13)
Interaction of phenyl 2-pyridyl ketoxime (PhPyCNO)/X(-)"blends" (X(-) = OH(-), Cl(-), ClO(4)(-), 2,4-D) (2,4-DH = 2,4-dichlorophenoxyacetic acid) with copper perchlorate has yielded trinuclear clusters that have been characterized as inverse-9-metallacrown-3, accommodating one or two anions. The structure of the complex [Cu(3)(PhPyCNO)(3)(mu(3)-OH)(2,4-D)(2)]
Constantina Papatriantafyllopoulou et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(4), 718-728 (2007-10-10)
The reactions of phenyl(2-pyridyl)ketone oxime (py)C(ph)NOH, with nickel(II) sulfate hexahydrate under reflux, in the absence of an external base, have been investigated. The reaction of NiSO4 x 6H2O with two equivalents of (py)C(ph)NOH in H2O/MeOH leads to the dinuclear complex
Ardeshir Shokrollahi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(2), 655-662 (2008-03-11)
The complexation reaction between some oximes including methyl-2-pyridylketone oxime (MPKO), phenyl-2-pyridylketone oxime (PPKO) and diacetyl monooxime (DMO) with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La3+ has been studied potentiometrically in aqueous solution

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