302155
(S)-(+)-1-苯基-1,2-乙二醇
99%
别名:
(+)-苯乙二醇, (S)-(+)-苯乙二醇
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关于此项目
线性分子式:
HOCH2CH(C6H5)OH
化学文摘社编号:
分子量:
138.16
Beilstein:
3196197
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
方案
99%
旋光性
[α]18/D +66°, c = 1 in chloroform
mp
64-67 °C (lit.)
官能团
hydroxyl
phenyl
SMILES字符串
OC[C@@H](O)c1ccccc1
InChI
1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m1/s1
InChI key
PWMWNFMRSKOCEY-MRVPVSSYSA-N
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储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
320.0 °F - closed cup
闪点(°C)
160.00 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Yawei Geng et al.
Wei sheng wu xue bao = Acta microbiologica Sinica, 50(1), 60-66 (2010-03-30)
A novel (S)-specific carbonyl reductase gene (scr II) was cloned from the genome of Candida parapsilosis CCTCC M203011, and its catalytic function for the biotransformation of chiral alcohol was verified. The possible carbonyl reductase gene scr II was amplified by
Yanbin Liu et al.
Journal of industrial microbiology & biotechnology, 33(4), 274-282 (2005-12-02)
A microorganism with the ability to catalyze the resolution of racemic phenyloxirane was isolated and identified as Aspergillus niger SQ-6. Chiral capillary electrophoresis was successfully applied to separate both phenyloxirane and phenylethanediol. The epoxide hydrolase (EH) involved in this resolution
Yao Nie et al.
Organic & biomolecular chemistry, 9(11), 4070-4078 (2011-04-21)
The application of biocatalysis to the synthesis of chiral molecules is one of the greenest technologies for the replacement of chemical routes due to its environmentally benign reaction conditions and unparalleled chemo-, regio- and stereoselectivities. We have been interested in
Qingsen Hu et al.
Bioresource technology, 101(22), 8502-8508 (2010-07-16)
Saccharomyces cerevisiae JUC15 was successfully obtained by target reaction-oriented screening, which reduced 2-hydroxy-1-phenylethanone (HPE) to (R)-phenyl-1,2-ethanediol ((R)-PED) of excellent enantiomeric excess (e.e. >99.9%). There was no significant decrease in the yield and optical purity of (R)-PED when the free cells
Y Nie et al.
Letters in applied microbiology, 44(5), 555-562 (2007-04-25)
To purify and characterize the (R)-specific carbonyl reductase from Candida parapsilosis; to compare the enzyme with other stereospecific oxidoreductases; and to develop an available procedure producing optically active (R)-1-phenyl-1,2-ethanediol (PED). An (R)-specific carbonyl reductase was found and purified from C.
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