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302155

(S)-(+)-1-苯基-1,2-乙二醇

Name: (<I>S</I>)-(+)-1-苯基-1,2-乙二醇
Brand: ALDRICH

99%

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别名:

(+)-苯乙二醇, (S)-(+)-苯乙二醇

线性分子式:

HOCH₂CH(C₆H₅)OH

CAS号:

25779-13-9

分子量:

138.16

Beilstein:

3196197

MDL编号:

MFCD00066256

PubChem化学物质编号:

24858237

NACRES:

NA.22

检测方案

99%

旋光性

[α]18/D +66°, c = 1 in chloroform

mp

64-67 °C (lit.)

SMILES string

OC[C@@H](O)c1ccccc1

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m1/s1

InChI key

PWMWNFMRSKOCEY-MRVPVSSYSA-N

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储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

320.0 °F - closed cup

闪点(°C)

160.00 °C - closed cup

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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Novel anti-Prelog stereospecific carbonyl reductases from Candida parapsilosis for asymmetric reduction of prochiral ketones.

Yao Nie et al.

Organic & biomolecular chemistry, 9(11), 4070-4078 (2011-04-21)

The application of biocatalysis to the synthesis of chiral molecules is one of the greenest technologies for the replacement of chemical routes due to its environmentally benign reaction conditions and unparalleled chemo-, regio- and stereoselectivities. We have been interested in

Protein engineering of epoxide hydrolase from Agrobacterium radiobacter AD1 for enhanced activity and enantioselective production of (R)-1-phenylethane-1,2-diol.

Lingyun Rui et al.

Applied and environmental microbiology, 71(7), 3995-4003 (2005-07-08)

DNA shuffling and saturation mutagenesis of positions F108, L190, I219, D235, and C248 were used to generate variants of the epoxide hydrolase of Agrobacterium radiobacter AD1 (EchA) with enhanced enantioselectivity and activity for styrene oxide and enhanced activity for 1,2-epoxyhexane

Enzymatic resolution of racemic phenyloxirane by a novel epoxide hydrolase from Aspergillus niger SQ-6 and its fed-batch fermentation.

Yanbin Liu et al.

Journal of industrial microbiology & biotechnology, 33(4), 274-282 (2005-12-02)

A microorganism with the ability to catalyze the resolution of racemic phenyloxirane was isolated and identified as Aspergillus niger SQ-6. Chiral capillary electrophoresis was successfully applied to separate both phenyloxirane and phenylethanediol. The epoxide hydrolase (EH) involved in this resolution

[Gene cloning and expression of a novel (S)-specific carbonyl reductase].

Yawei Geng et al.

Wei sheng wu xue bao = Acta microbiologica Sinica, 50(1), 60-66 (2010-03-30)

A novel (S)-specific carbonyl reductase gene (scr II) was cloned from the genome of Candida parapsilosis CCTCC M203011, and its catalytic function for the biotransformation of chiral alcohol was verified. The possible carbonyl reductase gene scr II was amplified by

Biosynthesis of (R)-phenyl-1,2-ethanediol from racemic styrene oxide by using bacterial and marine fish epoxide hydrolases.

Hee Sook Kim et al.

Biotechnology letters, 30(1), 127-133 (2007-08-01)

Enantio-convergent hydrolysis of racemic styrene oxides was achieved to prepare enantiopure (R)-phenyl-1,2-ethanediol by using two recombinant epoxide hydrolases (EHs) of a bacterium, Caulobacter crescentus, and a marine fish, Mugil cephalus. The recombinant C. crescentus EH primarily attacked the benzylic carbon

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(S)-(+)-1-苯基-1,2-乙二醇

99%

属性

检测方案

旋光性

mp

SMILES string

InChI

InChI key

相关类别

安全信息

储存分类代码

WGK

闪点(°F)

闪点(°C)

个人防护装备

法规信息

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