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线性分子式:
(CH3)2CHC(CH3)2Si(CH3)2Cl
化学文摘社编号:
分子量:
178.77
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3647960
Assay:
95%
Form:
liquid
InChI
1S/C8H19ClSi/c1-7(2)8(3,4)10(5,6)9/h7H,1-6H3
SMILES string
CC(C)C(C)(C)[Si](C)(C)Cl
InChI key
KIGALSBMRYYLFJ-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.449 (lit.)
bp
55-56 °C/10 mmHg (lit.)
density
0.909 g/mL at 25 °C (lit.)
Quality Level
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Application
醇类和其他官能团的保护剂。用于合成硅萘花青和环糊精衍生物,分别用作抗肿瘤染料和手性固定相。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
114.8 °F - closed cup
flash_point_c
46 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Journal of the Chemical Society. Perkin Transactions 1, 2585-2585 (1993)
Tetrahedron Asymmetry, 5, 347-347 (1994)
Aldrichimica Acta, 19, 52-52 (1986)
N Brasseur et al.
Journal of medicinal chemistry, 37(3), 415-420 (1994-02-04)
Bis(tert-butyldimethylsiloxy)- (7), bis(dimethylthexylsiloxy)- (8), bis(tri-n-hexylsiloxy)- (9), and bis(dimethyloctadecylsiloxy)silicon 2,3-naphthalocyanines (10) were prepared via substitution of the bis(hydroxy) precursor with the corresponding chlorosilane ligands and characterized by spectroscopic and combustion analyses. They show strong absorption around 780 nm where tissues exhibit
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