质量水平
检测方案
97%
reaction suitability
reagent type: reductant
mp
116-120 °C (dec.) (lit.)
SMILES string
[Na+].CC(=O)O[BH-](OC(C)=O)OC(C)=O
InChI
1S/C6H10BO6.Na/c1-4(8)11-7(12-5(2)9)13-6(3)10;/h7H,1-3H3;/q-1;+1
InChI key
HHYFEYBWNZJVFQ-UHFFFAOYSA-N
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相关类别
一般描述
应用
- 酮和醛的还原胺化。
- 与4-氧代戊酸甲酯和苄胺反应，通过还原胺化/内酰胺化制备N-苄基-γ-戊内酰胺。
- 将亚胺和烯胺还原成相应的胺。
- 将喹啉和异喹啉还原为相应的四氢衍生物。
- 烯烃的硼氢化。
- 合成氮氧双自由基，形成与树枝状大分子连接的高弛豫性末端基团。
相关产品
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Repr. 1B - Water-react 1
补充剂危害
储存分类代码
4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
分析证书(COA)
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示例
其它示例：
705578-5MG-PW
PL860-CGA/SHF-1EA
MMYOMAG-74K-13
1000309185
输入内容 1.000309185)
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如何查找COA批号
批号可以在产品标签上"批“ （Lot或Batch）字后面找到。
Aldrich 产品
如果您查询到的批号为 TO09019TO 等，请输入去除前两位字母的批号：09019TO。
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部分情况下，可能未在线提供COA。如果搜索不到COA，可在线索取。
Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.
How do I get lot-specific information or a Certificate of Analysis?
The lot specific COA document can be found by entering the lot number above under the "Documents" section.
What is Product 316393, Sodium triacetoxyborohydride, used for?
Sodium triacetoxyborohydride (NaBH(OAc)3) is particularly effective in reductive aminations due to its large scope, mildness, and selectivity.
Which is better to use, Product 316393, Sodium triacetoxyborohydride, or sodium cyanoborohydride?
It is preferred to sodium cyanoborohydride (NaBH3CN) in many applications due to reduced toxicity of the side products formed, and better yields and reproducibility during synthesis. (See Chemfiles, vol 5, no. 9). The reductive aminations of complex substrates also proceed smoothly using sodium triacetoxyborohydride.
How else can Product 316393, Sodium triacetoxyborohydride, be used as a reducing agent?
Recently, sodium triacetoxyborohydride was used to stereoselectively reduce 4-ketoprolines to the corresponding trans-hydroxy-proline in excellent yields. By comparison, reduction of the 4-ketoproline esters failed to provide any product.
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What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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商品
Sodium triacetoxyborohydride
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