assay
97%
form
solid
mp
71-74 °C (lit.)
SMILES string
C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
InChI key
NDUYAGLANMHJHF-UHFFFAOYSA-N
General description
Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.
Application
Allyltriphenylstannane can be used:
- As a reagent in the C-H phenylation of azoles catalyzed by palladium.
- As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)3.
- As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Allyltriphenylstannane
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Palladium-Catalyzed Direct Arylations of Azoles with Aryl Silicon and Tin Reagents
Han W, et al.
Chemistry?A European Journal , 17(25), 6904-6908 (2011)
Total synthesis of (+)-ambruticin S: probing the pharmacophoric subunit
Hanessian S, et al.
The Journal of Organic Chemistry, 75(16), 5601-5618 (2010)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 332364-50G | 04061833546734 |

