34310
2,3-二溴丙酸甲酯
≥97.0% (GC)
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线性分子式:
CH2BrCHBrCOOCH3
化学文摘社编号:
分子量:
245.90
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-044-3
Beilstein/REAXYS Number:
1750190
MDL number:
Assay:
≥97.0% (GC)
Form:
liquid
InChI key
ROXQOUUAPQUMLN-UHFFFAOYSA-N
InChI
1S/C4H6Br2O2/c1-8-4(7)3(6)2-5/h3H,2H2,1H3
SMILES string
COC(=O)C(Br)CBr
assay
≥97.0% (GC)
form
liquid
refractive index
n20/D 1.514
bp
83-86 °C/10 mmHg (lit.)
density
1.944 g/mL at 20 °C (lit.)
storage temp.
2-8°C
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Application
Methyl 2,3-dibromopropionate may be used in the preparation of methyl 2-azidoacrylate. It may be used in the preparation of methyl (+)-(1′R, 2R) and (-)-(1′R, 2S)-1-(2-phenylethanol)aziridine-2-carboxylates.
General description
Methyl 2,3-dibromopropionate is the methyl ester of 2,3-dibromopropanoic acid. It reacts with 2-acetamido-3-hydroxypyridine to give 2-substituted pyrido-oxazine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
2H-Azirines as dipolarophiles.
Pinho e Melo TMVD, et al.
Tetrahedron Letters, 44(33), 6313-6315 (2003)
Regiospecific and Enantiospecific Ring Opening of Methyl (+)-(1'R, 2R)-and (-)-(1'R, 2S)-1-(2-phenylethanol) Aziridine-2-carboxylates.
Gnecco D, et al.
Molecules (Basel), 5(8), 998-1003 (2000)
Synthesis of substituted 3, 4-dihydro-2< i> H</i>-pyrido [3, 2-< i> b</i>][1, 4] oxazine as new scaffolds for potential bioactive compounds.
Henry N, et al.
Tetrahedron, 62(10), 2405-2412 (2006)
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