所有图片(2)
About This Item
经验公式（希尔记法）:
C10H15NO3S
CAS号:
分子量:
229.30
Beilstein:
6274370
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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表单
solid
质量水平
旋光性
[α]28/D +45°, c = 2 in chloroform
杂质
<1% toluene
mp
172-174 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC1(C)[C@@H]2CC[C@]13CS(=O)(=O)N4O[C@@]34C2
InChI
1S/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1
InChI key
GBBJBUGPGFNISJ-YDQXZVTASA-N
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应用
(1S)-(+)-(10-樟脑磺酰)哑嗪可用于：
- 通过不对称氧化将前手性酮烯醇盐转化为旋光α-羟基酮。
- 通过焦磷酸连接的胸苷寡核苷酸合成。
- 从手性硫化物的DBU盐不对称合成质子泵抑制剂，如(R)-雷贝拉唑钠和(R)-兰索拉唑钠。
- 通过氧化相应氧膦基乙酸酯制备膦酰基乙酸酯和硫代膦酰基乙酸酯寡聚脱氧核苷酸。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
On the synthesis of oligonucleotides interconnected through pyrophosphate linkages
Kistemaker HAV, et al.
European Journal of Organic Chemistry, 2015(27), 6084-6091 (2015)
Davis oxaziridine-mediated asymmetric synthesis of proton pump inhibitors using DBU salt of prochiral sulfide
Mahale RD, et al.
Organic Process Research & Development, 14(5), 1264-1268 (2010)
Chemistry of oxaziridines. 14. Asymmetric oxidation of ketone enolates using enantiomerically pure (camphorylsulfonyl) oxaziridine
Davis FA, et al.
Journal of the American Chemical Society, 112(18), 6679-6690 (1990)
Douglas J Dellinger et al.
Journal of the American Chemical Society, 125(4), 940-950 (2003-01-23)
Phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides were prepared via a solid-phase synthesis strategy. Under Reformatsky reaction conditions, novel esterified acetic acid phosphinodiamidites were synthesized and condensed with appropriately protected 5'-O-(4, 4'-dimethoxytrityl)-2'-deoxynucleosides to yield 3'-O-phosphinoamidite reactive monomers. These synthons when activated with tetrazole
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