349585
苯甲酰二茂铁
≥98%
别名:
苯甲酰基二茂铁
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关于此项目
经验公式（希尔记法）:
C17H14FeO
化学文摘社编号:
分子量:
290.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
215-054-2
MDL number:
产品名称
苯甲酰二茂铁, ≥98%
InChI key
JJHHJZCYDPLHIL-UHFFFAOYSA-N
InChI
1S/C12H9O.C5H5.Fe/c13-12(11-8-4-5-9-11)10-6-2-1-3-7-10;1-2-4-5-3-1;/h1-9H;1-5H;
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.O=C([C]2[CH][CH][CH][CH]2)c3ccccc3
assay
≥98%
reaction suitability
core: iron
reagent type: catalyst
mp
105-107 °C (lit.)
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Application
Reactant for:
Reactant for synthesis of:
- Deprotonative metalation of ferrocenes
- Oxidative chemistry
- Reduction of ferrocenyl ketones
- Polymerization of C-ferrocenyl-substituted phosphaalkene
Reactant for synthesis of:
- Planat chiral triferrocenylmethane derivative
- Chiral ferrocenyl alcohols via asymmetric transfer hydrogenation
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Yong Leng Kelvin Tan et al.
Dalton transactions (Cambridge, England : 2003), 48(48), 10871-10881 (2009-12-22)
A series of compounds is described in which one of the ethyl groups in diethylstilbestrol has been replaced by a ferrocenyl substituent. Only those derivatives incorporating phenol moieties underwent isomerisation from the Z to the E form, and some of
Gandrath Dayaker et al.
Chemical communications (Cambridge, England), 46(16), 2862-2864 (2010-04-07)
A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.
H. Zhang and Z. Bian,
Journal of Organometallic Chemistry, 692, 5687-5689 (2007)
Y. Wu, et al.,
Tetrahedron Asymmetry, 20, 584-587 (2009)
J. R. Garabatos-Perera and H. Butenschoen,
Journal of Organometallic Chemistry, 694, 2047-2052 (2009)
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