Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.591 (lit.)
bp
98-100 °C/2 mmHg (lit.)
density
1.223 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
COC(=O)c1ccccc1S
InChI
1S/C8H8O2S/c1-10-8(9)6-4-2-3-5-7(6)11/h2-5,11H,1H3
InChI key
BAQGCWNPCFABAY-UHFFFAOYSA-N
General description
Methyl thiosalicylate may be benefecial in preventing mercury-induced toxicity.
Application
Methyl thiosalicylate may be used:
- in the synthesis of thioxanthone, an efficient enantioselective organocatalyst for the intramolecular [2+2] photocycloaddition reaction
- as anionic bidentate ligand, in the preparation of ′2+1′ type complexes of [(99m)Tc]-tricarbonyltechnetium(I) and [(188)Re]-tricarbonylrhenium(I)
- in the synthesis of a series of benzisothiazolone derivatives
- in the synthesis of a new fused benzoheterocyclic compound, [1]benzothieno[3,2-b]furan
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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Explore Nicewicz Photoredox catalysts—photoexcitable acridinium salts for efficient, metal-free anti-Markovnikov hydrofunctionalizations.
Rafael Alonso et al.
Angewandte Chemie (International ed. in English), 53(17), 4368-4371 (2014-03-22)
Thioxanthone 1, which was synthesized in a concise fashion from methyl thiosalicylate, exhibits a significant absorption in the visible light region. It allows for an efficient enantioselective catalysis of intramolecular [2+2] photocycloaddition reactions presumably by triplet energy transfer.
S Asadi et al.
International journal of immunopathology and pharmacology, 23(4), 1015-1020 (2011-01-20)
HgCl2 is a known environemental neurotoxin, but is also used as preservative in vaccines as thimerosal containing ethyl mercury covalently linked to thiosalicylate. We recently reported that mercury choloride (HgCl(2)) can stimulate human mast cells to release vascular endothelial growth
Synthesis of [1] Benzothieno [3, 2-b] furan-A New Fused Benzoheterocyclic System.
Svoboda J, et al.
Collection of Czechoslovak Chemical Communications, 58(12), 2983-2986 (1993)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 357758-25G | 04061837255113 |
| 357758-5G | 04061831812633 |