359068
(-)-二甲基-2,3-邻异丙亚基-L-酒石酸酯
97%
别名:
(4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-二羧酸二甲酯, (4R,5R)-2,2-二甲基-1,3-二氧戊环-4-羧酸甲酯
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关于此项目
经验公式（希尔记法）:
C9H14O6
化学文摘社编号:
分子量:
218.20
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
15406
产品名称
(-)-二甲基-2,3-邻异丙亚基-L-酒石酸酯, 97%
InChI
1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m1/s1
SMILES string
COC(=O)[C@@H]1OC(C)(C)O[C@H]1C(=O)OC
InChI key
ROZOUYVVWUTPNG-PHDIDXHHSA-N
assay
97%
form
liquid
optical activity
[α]20/D −54°, neat
refractive index
n20/D 1.439 (lit.)
bp
150 °C/19 mmHg (lit.)
density
1.190 g/mL at 20 °C (lit.)
functional group
ester
ether
ketal
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Application
TADDOL 手性助剂、联吡啶配体和苏糖醇的有用结构单元。
(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate may be used as a starting material in the total synthesis of (+)-migrastatin and also in the synthesis of a structural analog of S-ribosylhomocysteinase (LuxS), which acts as a potent competitive inhibitor against LuxS.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
Design and synthesis of substrate and intermediate analogue inhibitors of S-ribosylhomocysteinase.
Shen G, et al.
Journal of Medicinal Chemistry, 49(10), 3003-3011 (2006)
Tetrahedron Letters, 31, 7179-7179 (1990)
Angewandte Chemie (International Edition in English), 30, 99-99 (1991)
Organic Syntheses, 68, 92-92 (1990)
The total synthesis of (+)-migrastatin.
Gaul C, et al.
Journal of the American Chemical Society, 125(20), 6042-6043 (2003)
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