361771
3-异丙烯基-α,α-二甲基苄基异氰酸酯
contains ≤200 ppm BHT as inhibitor, 95%
别名:
3-异丙烯基-α,α′二甲基苄基异氰酸酯, m -异戊烯基-α,α′-二甲基苄基异氰酸酯
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关于此项目
线性分子式:
H2C=C(CH3)C6H4C(CH3)2NCO
化学文摘社编号:
分子量:
201.26
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
EC Number:
402-440-2
MDL number:
产品名称
3-异丙烯基-α,α-二甲基苄基异氰酸酯, contains ≤200 ppm BHT as inhibitor, 95%
assay
95%
InChI key
ZVEMLYIXBCTVOF-UHFFFAOYSA-N
InChI
1S/C13H15NO/c1-10(2)11-6-5-7-12(8-11)13(3,4)14-9-15/h5-8H,1H2,2-4H3
SMILES string
CC(=C)c1cccc(c1)C(C)(C)N=C=O
form
liquid
autoignition temp.
838 °F
contains
≤200 ppm BHT as inhibitor
refractive index
n20/D 1.53 (lit.)
bp
268-271 °C (lit.)
density
1.018 g/mL at 25 °C (lit.)
Quality Level
Application
m-TMI可用作四官能团异氰酸酯，其可进一步用于聚合物电解质的开发。 它可作为偶联剂用于制备黄麻纤维增强聚丙烯。
General description
3-异丙基-α,α-二甲基苄基异氰酸酯 (m-TMI) 是一种具有α-不饱和键和异氰酸酯端基的遥爪衍生物。它主要用于聚合物合成。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Inhalation
target_organs
Lungs
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
>212.0 °F - closed cup
flash_point_c
> 100 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Novel carbamoyl phosphonate monomers and polymers from unsaturated isocyanates
Ignatious F, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 31(1), 239-247 (1993)
Unexpected alternating radical copolymerization of chlorotrifluoroethylene with 3-isopropenyl-alpha, alpha$?-dimethylbenzyl isocyanate
Kyulavska M, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 48(12), 2681-2697 (2010)
Jute-polypropylene composites using m-TMI-grafted-polypropylene as a coupling agent
Aggarwal PK, et al.
Materials & Design, 43(1), 112-117 (2013)
Copolymerization behavior of 3-isopropenyl-alpha, alpha-dimethylbenzylamine and a preliminary evaluation of the copolymers in thermoset coatings
Trumbo DL, et al.
Journal of Applied Polymer Science, 82(4), 1030-1039 (2001)
G M Brauer et al.
Journal of biomedical materials research, 23(3), 295-309 (1989-03-01)
A series of methacrylate oligomers containing pendant isocyanate groups were synthesized by reacting 2-isocyanatoethyl methacrylate (IEM) and/or m-isopropenyl-alpha, alpha-dimethylbenzyl isocyanate (TMI) in ethoxyethyl acetate with methacrylates ranging from methyl to stearyl methacrylate or allyl-, cyclohexyl-, glycidyl-, i-bornyl-, or dicyclopentenyloxyethyl methacrylate.
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