364878
乙酸 1-溴羰基-1-甲基乙酯
≥95.0%
别名:
α-乙酰氧基异丁酰溴, 2-乙酰氧基异丁酰溴
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关于此项目
线性分子式:
CH3COOC(CH3)2COBr
化学文摘社编号:
分子量:
209.04
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2432585
产品名称
乙酸 1-溴羰基-1-甲基乙酯, ≥95.0%
InChI
1S/C6H9BrO3/c1-4(8)10-6(2,3)5(7)9/h1-3H3
SMILES string
CC(=O)OC(C)(C)C(Br)=O
InChI key
OOKAXSHFTDPZHP-UHFFFAOYSA-N
assay
≥95.0%
refractive index
n20/D 1.457 (lit.)
bp
75-77 °C/12 mmHg (lit.)
density
1.431 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
用于邻二醇脱氧反应的试剂，也可用于由对应的系列核糖核苷制备 2′,3′-二脱氧胞嘧啶核苷和其他二脱氧核苷和脱氧核苷。
General description
1-Bromocarbonyl-1-methylethyl acetate (α-Acetoxyisobutyryl bromide) participates in the conversion of adenosine to trans-3′(2′)-bromo-2′(3′)-acetates, via glycosyl cleavage.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Efficient synthesis of protected 3'-deoxyadenosine and 3'-deoxyguanosine from adenosine and guanosine.
Cui Z, et al.
Tetrahedron Letters, 42(4), 561-563 (2001)
Biphenyl dioxygenase-catalysed cis-dihydroxylation of tricyclic azaarenes: chemoenzymatic synthesis of arene oxide metabolites and furoquinoline alkaloids.
Boyd DR, et al.
Royal Society of Chemistry Advances, 3(27), 10944-10955 (2013)
Aldrichimica Acta, 23, 83-83 (1990)
A mild conversion of vicinal diols to alkenes. Efficient transformation of ribonucleosides into 2'-ene and 2t', 3'-dideoxynucleosides.
Robins MJ, et al.
Tetrahedron Letters, 25(4), 367-370 (1984)
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